Up-conversion characteristics of Er3+/Yb3+ co-doped heavy mental fluoride glass

Chun Feng He; Guan Shi Qin; Dan Zhao; Xiao Hong Chuai; Li Li Wang; Wei Ping Qin

doi:10.3788/OPE.20111913.0164

Up-conversion characteristics of Er³⁺/Yb³⁺ co-doped heavy mental fluoride glass

Chun Feng He
, Guan Shi Qin
, Dan Zhao
, Xiao Hong Chuai
, Li Li Wang
, Wei Ping Qin

Research output: Contribution to journal › Article › peer-review

Abstract

The up-conversion luminescence of Yb/Er co-doped 56ZrF₄-28BaF₂-2.5LnF₃ -4AlF₃-7NaF pumped by a 980 nm laser was studied and rich fluorescence lines were observed. It is shown that the peaks at 318.8, 380.6, 408.6, 453, 523, 545.5, 625.2, 653.8, 700.8 and 840.2 nm correspond to the transitions of ²P_3/2→⁴I_15/2, ⁴G_11/2→⁴I_15/2, ²H_9/2→⁴I_15/2, ⁴F_5/2→⁴I_15/2, ²H_11/2→⁴I_15/2, ⁴S_3/2→⁴I_15/2, ⁴F_5/2→⁴I_13/2, ⁴F_9/2→⁴I_15/2, ²H_9/2→⁴I_11/2 and ⁴S_3/2→⁴I_13/2, respectively. The concentrations influence of Yb and Er on the luminescence characteristics were described. The monotonically increasing up-conversion emission of Er³⁺ with the increase of Er³⁺ concentration was also observed. Furthermore, up-conversion mechanism was investigated in detail and it is attributed to the effective resonant energy transfer from Yb³⁺ to Er³⁺ ions in such system. The results provide a potential material for short wavelength up-conversion phosphor.

Original language	English
Pages (from-to)	164-168
Number of pages	5
Journal	Guangxue Jingmi Gongcheng/Optics and Precision Engineering
Volume	19
Issue number	7 SUPPL.
DOIs	https://doi.org/10.3788/OPE.20111913.0164
State	Published - Jul 2011
Externally published	Yes

Keywords

Heavy mental fluoride glass
Up-conversion uminescence
Yb/Er co-doping

Access to Document

10.3788/OPE.20111913.0164

Cite this

@article{9e2795ab98f24b398152b759decc069f,

title = "Up-conversion characteristics of Er3+/Yb3+ co-doped heavy mental fluoride glass",

abstract = "The up-conversion luminescence of Yb/Er co-doped 56ZrF4-28BaF2-2.5LnF3 -4AlF3-7NaF pumped by a 980 nm laser was studied and rich fluorescence lines were observed. It is shown that the peaks at 318.8, 380.6, 408.6, 453, 523, 545.5, 625.2, 653.8, 700.8 and 840.2 nm correspond to the transitions of 2P3/2→4I15/2, 4G11/2→4I15/2, 2H9/2→4I15/2, 4F5/2→4I15/2, 2H11/2→4I15/2, 4S3/2→4I15/2, 4F5/2→4I13/2, 4F9/2→4I15/2, 2H9/2→4I11/2 and 4S3/2→4I13/2, respectively. The concentrations influence of Yb and Er on the luminescence characteristics were described. The monotonically increasing up-conversion emission of Er3+ with the increase of Er3+ concentration was also observed. Furthermore, up-conversion mechanism was investigated in detail and it is attributed to the effective resonant energy transfer from Yb3+ to Er3+ ions in such system. The results provide a potential material for short wavelength up-conversion phosphor.",

keywords = "Heavy mental fluoride glass, Up-conversion uminescence, Yb/Er co-doping",

author = "He, \{Chun Feng\} and Qin, \{Guan Shi\} and Dan Zhao and Chuai, \{Xiao Hong\} and Wang, \{Li Li\} and Qin, \{Wei Ping\}",

year = "2011",

month = jul,

doi = "10.3788/OPE.20111913.0164",

language = "English",

volume = "19",

pages = "164--168",

journal = "Guangxue Jingmi Gongcheng/Optics and Precision Engineering",

issn = "1004-924X",

publisher = "Chinese Academy of Sciences",

number = "7 SUPPL.",

}

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T1 - Up-conversion characteristics of Er3+/Yb3+ co-doped heavy mental fluoride glass

AU - He, Chun Feng

AU - Qin, Guan Shi

AU - Zhao, Dan

AU - Chuai, Xiao Hong

AU - Wang, Li Li

AU - Qin, Wei Ping

PY - 2011/7

Y1 - 2011/7

N2 - The up-conversion luminescence of Yb/Er co-doped 56ZrF4-28BaF2-2.5LnF3 -4AlF3-7NaF pumped by a 980 nm laser was studied and rich fluorescence lines were observed. It is shown that the peaks at 318.8, 380.6, 408.6, 453, 523, 545.5, 625.2, 653.8, 700.8 and 840.2 nm correspond to the transitions of 2P3/2→4I15/2, 4G11/2→4I15/2, 2H9/2→4I15/2, 4F5/2→4I15/2, 2H11/2→4I15/2, 4S3/2→4I15/2, 4F5/2→4I13/2, 4F9/2→4I15/2, 2H9/2→4I11/2 and 4S3/2→4I13/2, respectively. The concentrations influence of Yb and Er on the luminescence characteristics were described. The monotonically increasing up-conversion emission of Er3+ with the increase of Er3+ concentration was also observed. Furthermore, up-conversion mechanism was investigated in detail and it is attributed to the effective resonant energy transfer from Yb3+ to Er3+ ions in such system. The results provide a potential material for short wavelength up-conversion phosphor.

AB - The up-conversion luminescence of Yb/Er co-doped 56ZrF4-28BaF2-2.5LnF3 -4AlF3-7NaF pumped by a 980 nm laser was studied and rich fluorescence lines were observed. It is shown that the peaks at 318.8, 380.6, 408.6, 453, 523, 545.5, 625.2, 653.8, 700.8 and 840.2 nm correspond to the transitions of 2P3/2→4I15/2, 4G11/2→4I15/2, 2H9/2→4I15/2, 4F5/2→4I15/2, 2H11/2→4I15/2, 4S3/2→4I15/2, 4F5/2→4I13/2, 4F9/2→4I15/2, 2H9/2→4I11/2 and 4S3/2→4I13/2, respectively. The concentrations influence of Yb and Er on the luminescence characteristics were described. The monotonically increasing up-conversion emission of Er3+ with the increase of Er3+ concentration was also observed. Furthermore, up-conversion mechanism was investigated in detail and it is attributed to the effective resonant energy transfer from Yb3+ to Er3+ ions in such system. The results provide a potential material for short wavelength up-conversion phosphor.

KW - Heavy mental fluoride glass

KW - Up-conversion uminescence

KW - Yb/Er co-doping

UR - https://www.scopus.com/pages/publications/81055156477

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IS - 7 SUPPL.