Thin films of ruthenium phthalocyanine complexes

Tristan Rawling, Christine E. Austin, Dominic Hare, Philip A. Doble, Hadi M. Zareie, Andrew M. McDonagh

Research output: Contribution to journalArticlepeer-review

8 Scopus citations


Four new ruthenium phthalocyanine complexes bearing axial ligands with thioacetate groups that facilitate thin film formation on gold surfaces are presented. Scanning tunnelling microscopy (STM) images and surface coverage data obtained by solution inductively coupled plasma mass spectrometry (ICP-MS) experiments show that peripheral and axial ligand substituents on the complexes have a significant effect on their surface coverage. A laser ablation ICP-MS technique that provides information about thin films across macro-sized areas is described here for the first time. Using the technique, the maximum surface coverage of a ruthenium phthalocyanine complex was found to occur within one minute of gold substrate immersion in the complex-containing solution.

Original languageEnglish
Pages (from-to)678-687
Number of pages10
JournalNano Research
Issue number9
StatePublished - Sep 2009
Externally publishedYes


  • Gold
  • Laser ablation
  • Phthalocyanine
  • Ruthenium
  • Surface


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