Synthesis, spectroscopic and thermal studies on ruthenium(III), rhodium(III) and iridium(III) complexes with hydrazones derived from 2,6-diacetylpyridine and different aromatic hydrazides

Vinod K. Sharma; Om P. Pandey; Soumitra K. Sengupta; Dost M. Halepoto

doi:10.1007/BF01098225

Synthesis, spectroscopic and thermal studies on ruthenium(III), rhodium(III) and iridium(III) complexes with hydrazones derived from 2,6-diacetylpyridine and different aromatic hydrazides

Vinod K. Sharma
, Om P. Pandey
, Soumitra K. Sengupta
, Dost M. Halepoto

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The reactions of MCl₃·3H₂O (M=Ru, Rh or Ir) with hydrazones have been studied by three different methods and complexes of the types [M(LH₂)(H₂O)₂]Cl₃, [M(L)Cl(H₂O)] and [M(LH₂)Cl₂]Cl·H₂O have been isolated. Tentative structural conclusions are drawn for these products based upon elemental analysis, electrical conductance, magnetic moment, and i.r. and¹H n.m.r. data. The thermal stability and mode of decomposition for the complexes have been studied by t.g.a., d.t.g. and d.s.c. techniques.

Original language	English
Pages (from-to)	263-266
Number of pages	4
Journal	Transition Metal Chemistry
Volume	14
Issue number	4
DOIs	https://doi.org/10.1007/BF01098225
State	Published - Aug 1989
Externally published	Yes

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10.1007/BF01098225

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@article{b32cbf4bf71d4391a564ac97ea482f95,

title = "Synthesis, spectroscopic and thermal studies on ruthenium(III), rhodium(III) and iridium(III) complexes with hydrazones derived from 2,6-diacetylpyridine and different aromatic hydrazides",

abstract = "The reactions of MCl3·3H2O (M=Ru, Rh or Ir) with hydrazones have been studied by three different methods and complexes of the types [M(LH2)(H2O)2]Cl3, [M(L)Cl(H2O)] and [M(LH2)Cl2]Cl·H2O have been isolated. Tentative structural conclusions are drawn for these products based upon elemental analysis, electrical conductance, magnetic moment, and i.r. and1H n.m.r. data. The thermal stability and mode of decomposition for the complexes have been studied by t.g.a., d.t.g. and d.s.c. techniques.",

author = "Sharma, \{Vinod K.\} and Pandey, \{Om P.\} and Sengupta, \{Soumitra K.\} and Halepoto, \{Dost M.\}",

year = "1989",

month = aug,

doi = "10.1007/BF01098225",

language = "English",

volume = "14",

pages = "263--266",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "4",

}

Synthesis, spectroscopic and thermal studies on ruthenium(III), rhodium(III) and iridium(III) complexes with hydrazones derived from 2,6-diacetylpyridine and different aromatic hydrazides. / Sharma, Vinod K.; Pandey, Om P.; Sengupta, Soumitra K. et al.
In: Transition Metal Chemistry, Vol. 14, No. 4, 08.1989, p. 263-266.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, spectroscopic and thermal studies on ruthenium(III), rhodium(III) and iridium(III) complexes with hydrazones derived from 2,6-diacetylpyridine and different aromatic hydrazides

AU - Sharma, Vinod K.

AU - Pandey, Om P.

AU - Sengupta, Soumitra K.

AU - Halepoto, Dost M.

PY - 1989/8

Y1 - 1989/8

N2 - The reactions of MCl3·3H2O (M=Ru, Rh or Ir) with hydrazones have been studied by three different methods and complexes of the types [M(LH2)(H2O)2]Cl3, [M(L)Cl(H2O)] and [M(LH2)Cl2]Cl·H2O have been isolated. Tentative structural conclusions are drawn for these products based upon elemental analysis, electrical conductance, magnetic moment, and i.r. and1H n.m.r. data. The thermal stability and mode of decomposition for the complexes have been studied by t.g.a., d.t.g. and d.s.c. techniques.

AB - The reactions of MCl3·3H2O (M=Ru, Rh or Ir) with hydrazones have been studied by three different methods and complexes of the types [M(LH2)(H2O)2]Cl3, [M(L)Cl(H2O)] and [M(LH2)Cl2]Cl·H2O have been isolated. Tentative structural conclusions are drawn for these products based upon elemental analysis, electrical conductance, magnetic moment, and i.r. and1H n.m.r. data. The thermal stability and mode of decomposition for the complexes have been studied by t.g.a., d.t.g. and d.s.c. techniques.

UR - https://www.scopus.com/pages/publications/0012774585

U2 - 10.1007/BF01098225

DO - 10.1007/BF01098225

M3 - Article

AN - SCOPUS:0012774585

SN - 0340-4285

VL - 14

SP - 263

EP - 266

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 4

ER -

Synthesis, spectroscopic and thermal studies on ruthenium(III), rhodium(III) and iridium(III) complexes with hydrazones derived from 2,6-diacetylpyridine and different aromatic hydrazides

Abstract

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