Synthesis, physico-chemical and antimicrobial studies on acetylferrocenyl hydrazone derivatives of dichlorobis(cyclopentadienyl)hafnium(IV)

Soumitra K. Sengupta, Om P. Pandey, Akhilesh K. Srivastava, Alpana Bhatt, Kushal N. Mishra

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

The reactions of Cp2HfCl2 with hydrazones (LH) derived from acetylferrocene and aromatic acid hydrazides (benzoic, 2-chlorobenzoic, 3-nitrobenzoic and 4-toluic) in various stoichiometric ratios have been studied and the complexes of the types [Cp2Hf(L)Cl] and [CpHf(L)3] were obtained. Tentative structural conclusions are drawn for the reaction products based upon elemental analyses, electrical conductance, magnetic moment and spectral data (u.v.-vis, i.r., 1H-n.m.r. and 13C-n.m.r.). Studies were conducted to assess the growth-inhibiting potential of the complexes synthesized, and the ligands, against various fungal and bacterial strains.

Original languageEnglish
Pages (from-to)703-707
Number of pages5
JournalTransition Metal Chemistry
Volume24
Issue number6
StatePublished - 1999
Externally publishedYes

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