Synthesis of two carbazole-based dyes and application of two-photon initiating polymerization

Rentao Hu; Liangfei Lü; Banfeng Ruan; Peng Wang; Mingliang Zhang; Hongping Zhou; Shengli Li; Jieying Wu; Yupeng Tian

doi:10.1007/s11426-009-0039-6

Synthesis of two carbazole-based dyes and application of two-photon initiating polymerization

Rentao Hu, Liangfei Lü, Banfeng Ruan, Peng Wang, Mingliang Zhang, Hongping Zhou, Shengli Li, Jieying Wu, Yupeng Tian

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Two carbazole-based polymerization initiators possessing blue fluorescence emission have been synthesized via Wittig reaction in the solid phase at room temperature. Two-photon excited fluorescence (TPEF) spectra for them were investigated under 800 nm fs laser pulse and two-photon absorption cross sections were determined by the Z-scan technique. Then two-photon initiating polymerization (TPIP) microfabrication experiments were successfully carried out. Three-dimensional lattice and artificial defects were gained, indicating that they were viable candidates for the two-photon polymerization initiator in practical application of microfabrication.

Original language	English
Pages (from-to)	1210-1215
Number of pages	6
Journal	Science in China, Series B: Chemistry
Volume	52
Issue number	8
DOIs	https://doi.org/10.1007/s11426-009-0039-6
State	Published - Aug 2009
Externally published	Yes

Keywords

Carbazole-based dye
Microfabrication
Two-photon excited fluorescence (TPEF)
Two-photon initiating polymerization (TPIP)

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10.1007/s11426-009-0039-6

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title = "Synthesis of two carbazole-based dyes and application of two-photon initiating polymerization",

abstract = "Two carbazole-based polymerization initiators possessing blue fluorescence emission have been synthesized via Wittig reaction in the solid phase at room temperature. Two-photon excited fluorescence (TPEF) spectra for them were investigated under 800 nm fs laser pulse and two-photon absorption cross sections were determined by the Z-scan technique. Then two-photon initiating polymerization (TPIP) microfabrication experiments were successfully carried out. Three-dimensional lattice and artificial defects were gained, indicating that they were viable candidates for the two-photon polymerization initiator in practical application of microfabrication.",

keywords = "Carbazole-based dye, Microfabrication, Two-photon excited fluorescence (TPEF), Two-photon initiating polymerization (TPIP)",

author = "Rentao Hu and Liangfei L{\"u} and Banfeng Ruan and Peng Wang and Mingliang Zhang and Hongping Zhou and Shengli Li and Jieying Wu and Yupeng Tian",

note = "Funding Information: Received October 28, 2008; accepted December 1, 2008 doi: 10.1007/s11426-009-0039-6 †Corresponding author (email: [email protected]; [email protected]) Supported by the National Natural Science Foundation of China (Grant Nos. 50532030, 20771001 & 50703001), and Team for Scientific Innovation of Anhui Province (Grant No. 2006KJ007TD)",

year = "2009",

month = aug,

doi = "10.1007/s11426-009-0039-6",

language = "English",

volume = "52",

pages = "1210--1215",

journal = "Science in China, Series B: Chemistry",

issn = "1006-9291",

publisher = "Gordon and Breach Science Publishers",

number = "8",

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TY - JOUR

T1 - Synthesis of two carbazole-based dyes and application of two-photon initiating polymerization

AU - Hu, Rentao

AU - Lü, Liangfei

AU - Ruan, Banfeng

AU - Wang, Peng

AU - Zhang, Mingliang

AU - Zhou, Hongping

AU - Li, Shengli

AU - Wu, Jieying

AU - Tian, Yupeng

N1 - Funding Information: Received October 28, 2008; accepted December 1, 2008 doi: 10.1007/s11426-009-0039-6 †Corresponding author (email: [email protected]; [email protected]) Supported by the National Natural Science Foundation of China (Grant Nos. 50532030, 20771001 & 50703001), and Team for Scientific Innovation of Anhui Province (Grant No. 2006KJ007TD)

PY - 2009/8

Y1 - 2009/8

N2 - Two carbazole-based polymerization initiators possessing blue fluorescence emission have been synthesized via Wittig reaction in the solid phase at room temperature. Two-photon excited fluorescence (TPEF) spectra for them were investigated under 800 nm fs laser pulse and two-photon absorption cross sections were determined by the Z-scan technique. Then two-photon initiating polymerization (TPIP) microfabrication experiments were successfully carried out. Three-dimensional lattice and artificial defects were gained, indicating that they were viable candidates for the two-photon polymerization initiator in practical application of microfabrication.

AB - Two carbazole-based polymerization initiators possessing blue fluorescence emission have been synthesized via Wittig reaction in the solid phase at room temperature. Two-photon excited fluorescence (TPEF) spectra for them were investigated under 800 nm fs laser pulse and two-photon absorption cross sections were determined by the Z-scan technique. Then two-photon initiating polymerization (TPIP) microfabrication experiments were successfully carried out. Three-dimensional lattice and artificial defects were gained, indicating that they were viable candidates for the two-photon polymerization initiator in practical application of microfabrication.

KW - Carbazole-based dye

KW - Microfabrication

KW - Two-photon excited fluorescence (TPEF)

KW - Two-photon initiating polymerization (TPIP)

UR - http://www.scopus.com/inward/record.url?scp=68649123854&partnerID=8YFLogxK

U2 - 10.1007/s11426-009-0039-6

DO - 10.1007/s11426-009-0039-6

M3 - Article

AN - SCOPUS:68649123854

SN - 1006-9291

VL - 52

SP - 1210

EP - 1215

JO - Science in China, Series B: Chemistry

JF - Science in China, Series B: Chemistry

IS - 8

ER -

Synthesis of two carbazole-based dyes and application of two-photon initiating polymerization

Abstract

Keywords

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