Synthesis of fac-[Fe II(CN)(CO) 3I 2] - and chemistry of the fac-[Fe II(CN) x(CO) 3I (3 - X)] - series (x = 1-3)

Aryeh Stock; Ofir Azran; Benjamin Garden; Jonathan Solaimanzadeh; Wenfeng Lo; Jiangfeng Jiang

doi:10.1016/j.inoche.2012.01.028

Synthesis of fac-[Fe ^II(CN)(CO) ₃I ₂] ^- and chemistry of the fac-[Fe ^II(CN) _x(CO) ₃I _{(3 - X)}] ^- series (x = 1-3)

Aryeh Stock
, Ofir Azran
, Benjamin Garden
, Jonathan Solaimanzadeh
, Wenfeng Lo
, Jiangfeng Jiang

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Whole series of fac-[Fe ^II(CN) _x(CO) ₃I _{(3 - x)}] ^- (x = 1-3) generated by stepwise replacement of iodide from fac-[Fe ^II(CO) ₃I ₃] ^- by cyanide were isolated and structurally characterized. The infrared trend of this series demonstrates the effect of the electronic properties of ligands on the coordinated CO stretching frequencies.

Original language	English
Pages (from-to)	105-109
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	18
DOIs	https://doi.org/10.1016/j.inoche.2012.01.028
State	Published - Apr 2012
Externally published	Yes

Keywords

Carbonyl
Cyanide
Infrared
Structure
Substitution reaction

Access to Document

10.1016/j.inoche.2012.01.028

Cite this

@article{3231d6a6b9574bd59982f7f5973c6c0d,

title = "Synthesis of fac-[Fe II(CN)(CO) 3I 2] - and chemistry of the fac-[Fe II(CN) x(CO) 3I (3 - X)] - series (x = 1-3)",

abstract = "Whole series of fac-[Fe II(CN) x(CO) 3I (3 - x)] - (x = 1-3) generated by stepwise replacement of iodide from fac-[Fe II(CO) 3I 3] - by cyanide were isolated and structurally characterized. The infrared trend of this series demonstrates the effect of the electronic properties of ligands on the coordinated CO stretching frequencies.",

keywords = "Carbonyl, Cyanide, Infrared, Structure, Substitution reaction",

author = "Aryeh Stock and Ofir Azran and Benjamin Garden and Jonathan Solaimanzadeh and Wenfeng Lo and Jiangfeng Jiang",

note = "Funding Information: This research is supported by Yeshiva University and Petroleum Research Fund ( UNI \#49424 ). ",

year = "2012",

month = apr,

doi = "10.1016/j.inoche.2012.01.028",

language = "English",

volume = "18",

pages = "105--109",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Synthesis of fac-[Fe II(CN)(CO) 3I 2] - and chemistry of the fac-[Fe II(CN) x(CO) 3I (3 - X)] - series (x = 1-3)

AU - Stock, Aryeh

AU - Azran, Ofir

AU - Garden, Benjamin

AU - Solaimanzadeh, Jonathan

AU - Lo, Wenfeng

AU - Jiang, Jiangfeng

N1 - Funding Information: This research is supported by Yeshiva University and Petroleum Research Fund ( UNI #49424 ).

PY - 2012/4

Y1 - 2012/4

N2 - Whole series of fac-[Fe II(CN) x(CO) 3I (3 - x)] - (x = 1-3) generated by stepwise replacement of iodide from fac-[Fe II(CO) 3I 3] - by cyanide were isolated and structurally characterized. The infrared trend of this series demonstrates the effect of the electronic properties of ligands on the coordinated CO stretching frequencies.

AB - Whole series of fac-[Fe II(CN) x(CO) 3I (3 - x)] - (x = 1-3) generated by stepwise replacement of iodide from fac-[Fe II(CO) 3I 3] - by cyanide were isolated and structurally characterized. The infrared trend of this series demonstrates the effect of the electronic properties of ligands on the coordinated CO stretching frequencies.

KW - Carbonyl

KW - Cyanide

KW - Infrared

KW - Structure

KW - Substitution reaction

UR - https://www.scopus.com/pages/publications/84857993721

U2 - 10.1016/j.inoche.2012.01.028

DO - 10.1016/j.inoche.2012.01.028

M3 - Article

AN - SCOPUS:84857993721

SN - 1387-7003

VL - 18

SP - 105

EP - 109

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications