Synthesis, crystal structures, and two-photon absorption properties of dithiocarbazate Zn(II) and Pd(II) complexes

Hong ping Zhou; Dong mei Li; Peng Wang; Le hua Cheng; Yuan hao Gao; Yong min Zhu; Jie ying Wu; Yu peng Tian; Xu tang Tao; Min hua Jiang; Hoong Kun Fun

doi:10.1016/j.molstruc.2006.05.003

Synthesis, crystal structures, and two-photon absorption properties of dithiocarbazate Zn(II) and Pd(II) complexes

Hong ping Zhou, Dong mei Li, Peng Wang, Le hua Cheng, Yuan hao Gao, Yong min Zhu, Jie ying Wu, Yu peng Tian, Xu tang Tao, Min hua Jiang, Hoong Kun Fun

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

A new bidentate Schiff base ligand (abbreviated as L) derived from the condensation of S-methyldithiocarbazate (SMDTC) with 9-fluorenone, and its complexes ML₂ (M = Ni(II), Zn(II) and Pd(II)) have been synthesized and fully characterized by elemental analyses, IR, molar conductivity and UV-vis spectroscopy. The structures of complexes ZnL₂ and PdL₂ have been determined by X-ray diffraction analysis. Complex ZnL₂ adopts a distorted tetrahedral geometry with the azomethine nitrogen atom and the thiolate sulfur atom. The coordination geometry about the Pd(II) is surprisingly a cis-configuration square-planar formed by the Pd(II) atom coordinating to the NS bidentate ligand. Detailed crystal structure analyses show that the cis-positioning of the two ligands was stabilized by the π-π stacking interactions between the two delocalized diazafluorene moieties. The two-photon absorption of L and ML₂ solutions (in DMF) was measured at 532 nm by the open-aperture Z-scan technique.

Original language	English
Pages (from-to)	205-210
Number of pages	6
Journal	Journal of Molecular Structure
Volume	826
Issue number	2-3
DOIs	https://doi.org/10.1016/j.molstruc.2006.05.003
State	Published - 29 Jan 2007
Externally published	Yes

Keywords

Dithiocarbazate
Fluorenone
Schiff base
π-π stacking

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10.1016/j.molstruc.2006.05.003

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@article{5d9a5cf65d554f9e8d25037d77d96f76,

title = "Synthesis, crystal structures, and two-photon absorption properties of dithiocarbazate Zn(II) and Pd(II) complexes",

abstract = "A new bidentate Schiff base ligand (abbreviated as L) derived from the condensation of S-methyldithiocarbazate (SMDTC) with 9-fluorenone, and its complexes ML2 (M = Ni(II), Zn(II) and Pd(II)) have been synthesized and fully characterized by elemental analyses, IR, molar conductivity and UV-vis spectroscopy. The structures of complexes ZnL2 and PdL2 have been determined by X-ray diffraction analysis. Complex ZnL2 adopts a distorted tetrahedral geometry with the azomethine nitrogen atom and the thiolate sulfur atom. The coordination geometry about the Pd(II) is surprisingly a cis-configuration square-planar formed by the Pd(II) atom coordinating to the NS bidentate ligand. Detailed crystal structure analyses show that the cis-positioning of the two ligands was stabilized by the π-π stacking interactions between the two delocalized diazafluorene moieties. The two-photon absorption of L and ML2 solutions (in DMF) was measured at 532 nm by the open-aperture Z-scan technique.",

keywords = "Dithiocarbazate, Fluorenone, Schiff base, π-π stacking",

author = "Zhou, {Hong ping} and Li, {Dong mei} and Peng Wang and Cheng, {Le hua} and Gao, {Yuan hao} and Zhu, {Yong min} and Wu, {Jie ying} and Tian, {Yu peng} and Tao, {Xu tang} and Jiang, {Min hua} and Fun, {Hoong Kun}",

note = "Funding Information: We thank National Natural Science Foundation of China (50532030, 50325311, 50335050), Doctoral Program Foundation of the Ministry of Education of China, Education of Committee of Anhui Province (2006KJ032A, 2006KJ135B), Person with Ability Foundation of Anhui Province 2002Z021, The team for Scientific Innovation Foundation of Anhui Province (2006KJ007TD). ",

year = "2007",

month = jan,

day = "29",

doi = "10.1016/j.molstruc.2006.05.003",

language = "English",

volume = "826",

pages = "205--210",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "2-3",

}

TY - JOUR

T1 - Synthesis, crystal structures, and two-photon absorption properties of dithiocarbazate Zn(II) and Pd(II) complexes

AU - Zhou, Hong ping

AU - Li, Dong mei

AU - Wang, Peng

AU - Cheng, Le hua

AU - Gao, Yuan hao

AU - Zhu, Yong min

AU - Wu, Jie ying

AU - Tian, Yu peng

AU - Tao, Xu tang

AU - Jiang, Min hua

AU - Fun, Hoong Kun

N1 - Funding Information: We thank National Natural Science Foundation of China (50532030, 50325311, 50335050), Doctoral Program Foundation of the Ministry of Education of China, Education of Committee of Anhui Province (2006KJ032A, 2006KJ135B), Person with Ability Foundation of Anhui Province 2002Z021, The team for Scientific Innovation Foundation of Anhui Province (2006KJ007TD).

PY - 2007/1/29

Y1 - 2007/1/29

N2 - A new bidentate Schiff base ligand (abbreviated as L) derived from the condensation of S-methyldithiocarbazate (SMDTC) with 9-fluorenone, and its complexes ML2 (M = Ni(II), Zn(II) and Pd(II)) have been synthesized and fully characterized by elemental analyses, IR, molar conductivity and UV-vis spectroscopy. The structures of complexes ZnL2 and PdL2 have been determined by X-ray diffraction analysis. Complex ZnL2 adopts a distorted tetrahedral geometry with the azomethine nitrogen atom and the thiolate sulfur atom. The coordination geometry about the Pd(II) is surprisingly a cis-configuration square-planar formed by the Pd(II) atom coordinating to the NS bidentate ligand. Detailed crystal structure analyses show that the cis-positioning of the two ligands was stabilized by the π-π stacking interactions between the two delocalized diazafluorene moieties. The two-photon absorption of L and ML2 solutions (in DMF) was measured at 532 nm by the open-aperture Z-scan technique.

AB - A new bidentate Schiff base ligand (abbreviated as L) derived from the condensation of S-methyldithiocarbazate (SMDTC) with 9-fluorenone, and its complexes ML2 (M = Ni(II), Zn(II) and Pd(II)) have been synthesized and fully characterized by elemental analyses, IR, molar conductivity and UV-vis spectroscopy. The structures of complexes ZnL2 and PdL2 have been determined by X-ray diffraction analysis. Complex ZnL2 adopts a distorted tetrahedral geometry with the azomethine nitrogen atom and the thiolate sulfur atom. The coordination geometry about the Pd(II) is surprisingly a cis-configuration square-planar formed by the Pd(II) atom coordinating to the NS bidentate ligand. Detailed crystal structure analyses show that the cis-positioning of the two ligands was stabilized by the π-π stacking interactions between the two delocalized diazafluorene moieties. The two-photon absorption of L and ML2 solutions (in DMF) was measured at 532 nm by the open-aperture Z-scan technique.

KW - Dithiocarbazate

KW - Fluorenone

KW - Schiff base

KW - π-π stacking

UR - http://www.scopus.com/inward/record.url?scp=33845996614&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2006.05.003

DO - 10.1016/j.molstruc.2006.05.003

M3 - Article

AN - SCOPUS:33845996614

SN - 0022-2860

VL - 826

SP - 205

EP - 210

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 2-3

ER -

Synthesis, crystal structures, and two-photon absorption properties of dithiocarbazate Zn(II) and Pd(II) complexes

Abstract

Keywords

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