Synthesis and structural studies on mono- And bis(cyclopentadienyl)titanium(IV)/zirconium(IV) derivatives of ferrocenyl hydrazones

  • S. K. Srivastava
  • , B. K. Srivastava
  • , N. Gupta
  • , O. P. Pandey
  • , S. K. Sengupta

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

The reactions of hydrazones, derived by the condensation of acetylferrocene with different aromatic acid hydrazides (benzoic, 2-chlorobenzoic, nitrobenzoic, methylbenzoic), with mono(cyclopentadienyl)titanium(IV) trichloride and bis(cyclopentadienyl) titanium (IV)/zirconium (IV) dichloride have been studied in anhydrous tetrahydrofuran or dichloromethane in the presence and absence of amine. Tentative structural conclusions are drawn for the reaction products based upon elemental analysis, electrical conductance, magnetic moment and spectral (electronic, infrared and 1H NMR) data.

Original languageEnglish
Pages (from-to)778-782
Number of pages5
JournalIndian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume36
Issue number9
StatePublished - 1997
Externally publishedYes

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