Synthesis and structural studies of mono(cyclopentadienyl)titanium(IV) derivatives of acetylferrocenyl thiosemicarbazones

S. K. Sengupta, O. P. Pandey, A. K. Srivastava, S. K. Srivastava

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

The reactions of thiosemicarbazones, derived by the condensation of acetylferrocene and different thiosemicarbazides (phenyl thiosemicarbazidel 4-chlorophenyl thiosemicarbazide, 4-nitrophenyl thiosemicarbazide, 2- methylphenyl thiosemicarbazide. 4-methylphenylthiosemicarbazide), with mono(cyclopentadienyl)titanium(IV) chloride have been studied in anhydrous tetrahydrofuran in the presence of amine. Tentative structural conclusions are drawn for the reaction products based upon elemental analyses, electrical conductance, magnetic moment and spectral (electronic, infrared and 1H NMR) data.

Original languageEnglish
Pages (from-to)1066-1069
Number of pages4
JournalIndian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume38
Issue number10
StatePublished - Oct 1999
Externally publishedYes

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