Synthesis and structural studies of mono- and bis-n5-cyclopentadienyl)hafnium(IV) derivatives of heterocyclic thioketones

Om Prakash Pandey

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7 Scopus citations

Abstract

The reactions of dichlorobis(n5-cyclopentadienyl)hafnium(IV) with four different classes of heterocyclic thioketone viz., 3-substituted-4-amino-S-triazole-5-thiol, 1-substituted-2-thiohydantoin, 5-substituted 1, 3, 4-oxadiazole-2-thione and 1-substituted tetrazoline-5-thione were studied in anhydrous tetrahydrofuran in the presence of base. The reaction products were characterized on the basis of elemental analyses, electrical conductance, magnetic susceptibility and spectral (electronic, infrared and1H n.m.r.) data.

Original languageEnglish
Pages (from-to)521-524
Number of pages4
JournalTransition Metal Chemistry
Volume12
Issue number6
DOIs
StatePublished - Dec 1987
Externally publishedYes

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