Synthesis and physicochemical studies on ruthenium(III) and rhodium(III) complexes with chalcone oximes

V. K. Sharma, O. P. Pandey, S. K. Sengupta

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12 Scopus citations

Abstract

The reactions of ruthenium(III) and rhodium(III) chloride with neutral chalcone oximes (COxH), 2-hydroxychalcone oximes (COx'H2), 2'-hydroxychalcone oxime (SCOx”H2) and 2,2'-dihydroxychalcone oxime (DCOx” 'H3) have been studied in absolute ethanol and complexes of types [M(COxH)3Cl3], [M(COx'H)3], [M(SCOx”H)3] and [M(DCOx” 'H2)2Cl] have been isolated, and characterized on the basis of elemental analyses, electrical conductance, magnetic moment and spectral (electronic, infrared and 1H n.m.r.) data. The probable structures of the complexes are suggested.

Original languageEnglish
Pages (from-to)1587-1599
Number of pages13
JournalSynthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume21
Issue number10
DOIs
StatePublished - 1 Dec 1991
Externally publishedYes

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