Synthesis and characterization of acetylferrocenyl thiosemicarbazone derivatives of dichlorobis(cyclopentadienyl)hafnium(IV)

Soumitra Kumar Sengupta; Om Prakash Pandey; Alpana Bhatt; Vinita Srivastava; Kushal Nath Mishra

Synthesis and characterization of acetylferrocenyl thiosemicarbazone derivatives of dichlorobis(cyclopentadienyl)hafnium(IV)

Soumitra Kumar Sengupta
, Om Prakash Pandey
, Alpana Bhatt
, Vinita Srivastava
, Kushal Nath Mishra

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The reactions of Cp₂HfCl₂ with thiosemicarbazones (LH) derived from acetylferrocene and substituted thiosemicarbazide (phenyl/4-chlorophenyl/4-nitrophenyl/4-methylphenyl thiosemicarbazide) in various stoichiometric ratios have been studied and the complexes of the type [Cp₂HfCl(L)] are obtained. Tentative structural conclusions are drawn for the reaction products based upon elemental analyses, electrical conductance, magnetic moment and spectral data (UV-Vis, IR, ¹H NMR and ¹³C NMR).

Original language	English
Pages (from-to)	1421-1423
Number of pages	3
Journal	Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume	41
Issue number	7
State	Published - Jul 2002
Externally published	Yes

Cite this

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title = "Synthesis and characterization of acetylferrocenyl thiosemicarbazone derivatives of dichlorobis(cyclopentadienyl)hafnium(IV)",

abstract = "The reactions of Cp2HfCl2 with thiosemicarbazones (LH) derived from acetylferrocene and substituted thiosemicarbazide (phenyl/4-chlorophenyl/4-nitrophenyl/4-methylphenyl thiosemicarbazide) in various stoichiometric ratios have been studied and the complexes of the type [Cp2HfCl(L)] are obtained. Tentative structural conclusions are drawn for the reaction products based upon elemental analyses, electrical conductance, magnetic moment and spectral data (UV-Vis, IR, 1H NMR and 13C NMR).",

author = "Sengupta, \{Soumitra Kumar\} and Pandey, \{Om Prakash\} and Alpana Bhatt and Vinita Srivastava and Mishra, \{Kushal Nath\}",

year = "2002",

month = jul,

language = "English",

volume = "41",

pages = "1421--1423",

journal = "Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry",

issn = "0376-4710",

publisher = "Scientific Publishers of India",

number = "7",

}

Synthesis and characterization of acetylferrocenyl thiosemicarbazone derivatives of dichlorobis(cyclopentadienyl)hafnium(IV). / Sengupta, Soumitra Kumar; Pandey, Om Prakash; Bhatt, Alpana et al.
In: Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, Vol. 41, No. 7, 07.2002, p. 1421-1423.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and characterization of acetylferrocenyl thiosemicarbazone derivatives of dichlorobis(cyclopentadienyl)hafnium(IV)

AU - Sengupta, Soumitra Kumar

AU - Pandey, Om Prakash

AU - Bhatt, Alpana

AU - Srivastava, Vinita

AU - Mishra, Kushal Nath

PY - 2002/7

Y1 - 2002/7

N2 - The reactions of Cp2HfCl2 with thiosemicarbazones (LH) derived from acetylferrocene and substituted thiosemicarbazide (phenyl/4-chlorophenyl/4-nitrophenyl/4-methylphenyl thiosemicarbazide) in various stoichiometric ratios have been studied and the complexes of the type [Cp2HfCl(L)] are obtained. Tentative structural conclusions are drawn for the reaction products based upon elemental analyses, electrical conductance, magnetic moment and spectral data (UV-Vis, IR, 1H NMR and 13C NMR).

AB - The reactions of Cp2HfCl2 with thiosemicarbazones (LH) derived from acetylferrocene and substituted thiosemicarbazide (phenyl/4-chlorophenyl/4-nitrophenyl/4-methylphenyl thiosemicarbazide) in various stoichiometric ratios have been studied and the complexes of the type [Cp2HfCl(L)] are obtained. Tentative structural conclusions are drawn for the reaction products based upon elemental analyses, electrical conductance, magnetic moment and spectral data (UV-Vis, IR, 1H NMR and 13C NMR).

UR - https://www.scopus.com/pages/publications/0036650842

M3 - Article

AN - SCOPUS:0036650842

SN - 0376-4710

VL - 41

SP - 1421

EP - 1423

JO - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry

JF - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry

IS - 7

ER -

Synthesis and characterization of acetylferrocenyl thiosemicarbazone derivatives of dichlorobis(cyclopentadienyl)hafnium(IV)

Abstract

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