Synthesis and characterization of acetylferrocenyl thiosemicarbazone derivatives of dichlorobis(cyclopentadienyl)hafnium(IV)

Soumitra Kumar Sengupta, Om Prakash Pandey, Alpana Bhatt, Vinita Srivastava, Kushal Nath Mishra

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

The reactions of Cp2HfCl2 with thiosemicarbazones (LH) derived from acetylferrocene and substituted thiosemicarbazide (phenyl/4-chlorophenyl/4-nitrophenyl/4-methylphenyl thiosemicarbazide) in various stoichiometric ratios have been studied and the complexes of the type [Cp2HfCl(L)] are obtained. Tentative structural conclusions are drawn for the reaction products based upon elemental analyses, electrical conductance, magnetic moment and spectral data (UV-Vis, IR, 1H NMR and 13C NMR).

Original languageEnglish
Pages (from-to)1421-1423
Number of pages3
JournalIndian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume41
Issue number7
StatePublished - Jul 2002
Externally publishedYes

Fingerprint

Dive into the research topics of 'Synthesis and characterization of acetylferrocenyl thiosemicarbazone derivatives of dichlorobis(cyclopentadienyl)hafnium(IV)'. Together they form a unique fingerprint.

Cite this