Synthesis and characterization of a novel three-dimensional open-framework: Metal diphosphonate, Zn[HO3PCH2(C6H4)CH2PO3H]

Xianzhu Xu; Peng Wang; Rong Hao; Meina Gan; Fuxing Sun; Guang shan Zhu

doi:10.1016/j.solidstatesciences.2008.06.004

Synthesis and characterization of a novel three-dimensional open-framework: Metal diphosphonate, Zn[HO₃PCH₂(C₆H₄)CH₂PO₃H]

Xianzhu Xu
, Peng Wang
, Rong Hao
, Meina Gan
, Fuxing Sun
, Guang shan Zhu

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A novel zinc diphosphonate, Zn[HO₃PCH₂(C₆H₄)CH₂PO₃H] (1) was synthesized from tetraethyl para-xylylenediphosphonate, Et₂O₃PCH₂C₆H₄CH₂PO₃Et₂, and Zn (AcO)₂·2H₂O under solvothermal conditions. The structure of compound 1 was determined by single-crystal X-ray diffraction, which reveals that the structure crystallizes in the monoclinic space group C2/c (No. 15), with a = 22.4844(19) Å, b = 6.4361(5) Å, c = 8.1194(7) Å, β = 102.595(2)°, V = 1146.70(16) Å³, T = 298(2) K, Z = 8. The novel three-dimensional (3D) construction is simply built up from linear inorganic chains of corner-sharing four-rings of tetrahedral [ZnO₄] and [PO₃C] which connected adjacent chains by the organophosphorus ligand para-xylylenediphosphonate. The framework has 10 Å × 4 Å (containing the van der Waals radii of atoms) channels running along the b-axis.

Original language	English
Pages (from-to)	68-71
Number of pages	4
Journal	Solid State Sciences
Volume	11
Issue number	1
DOIs	https://doi.org/10.1016/j.solidstatesciences.2008.06.004
State	Published - Jan 2009
Externally published	Yes

Keywords

Diphosphonate
Open-framework
Organic-inorganic hybrid
Solvothermal

Access to Document

10.1016/j.solidstatesciences.2008.06.004

Cite this

@article{aedbe59888564299a7afc9400b923307,

title = "Synthesis and characterization of a novel three-dimensional open-framework: Metal diphosphonate, Zn[HO3PCH2(C6H4)CH2PO3H]",

abstract = "A novel zinc diphosphonate, Zn[HO3PCH2(C6H4)CH2PO3H] (1) was synthesized from tetraethyl para-xylylenediphosphonate, Et2O3PCH2C6H4CH2PO3Et2, and Zn (AcO)2·2H2O under solvothermal conditions. The structure of compound 1 was determined by single-crystal X-ray diffraction, which reveals that the structure crystallizes in the monoclinic space group C2/c (No. 15), with a = 22.4844(19) {\AA}, b = 6.4361(5) {\AA}, c = 8.1194(7) {\AA}, β = 102.595(2)°, V = 1146.70(16) {\AA}3, T = 298(2) K, Z = 8. The novel three-dimensional (3D) construction is simply built up from linear inorganic chains of corner-sharing four-rings of tetrahedral [ZnO4] and [PO3C] which connected adjacent chains by the organophosphorus ligand para-xylylenediphosphonate. The framework has 10 {\AA} × 4 {\AA} (containing the van der Waals radii of atoms) channels running along the b-axis.",

keywords = "Diphosphonate, Open-framework, Organic-inorganic hybrid, Solvothermal",

author = "Xianzhu Xu and Peng Wang and Rong Hao and Meina Gan and Fuxing Sun and Zhu, \{Guang shan\}",

note = "Funding Information: We are grateful to the NSFC of China (Grant nos. 50678045, 20571030, 20531030 and 20371020), NSF of Heilongjiang Province (Grant no. E200519), Postdoctoral Foundation of China, Postdoctoral Imbursement Foundation of Heilongjiang Province, the State Basic Research Project (No. 2006CB806100), outstanding Young Scientist Foundation of NSFC (20625102), “111” programe of Ministry of Education and Science and Technology Bureau of Jilin Province.",

year = "2009",

month = jan,

doi = "10.1016/j.solidstatesciences.2008.06.004",

language = "English",

volume = "11",

pages = "68--71",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier Masson s.r.l.",

number = "1",

}

TY - JOUR

T1 - Synthesis and characterization of a novel three-dimensional open-framework

T2 - Metal diphosphonate, Zn[HO3PCH2(C6H4)CH2PO3H]

AU - Xu, Xianzhu

AU - Wang, Peng

AU - Hao, Rong

AU - Gan, Meina

AU - Sun, Fuxing

AU - Zhu, Guang shan

N1 - Funding Information: We are grateful to the NSFC of China (Grant nos. 50678045, 20571030, 20531030 and 20371020), NSF of Heilongjiang Province (Grant no. E200519), Postdoctoral Foundation of China, Postdoctoral Imbursement Foundation of Heilongjiang Province, the State Basic Research Project (No. 2006CB806100), outstanding Young Scientist Foundation of NSFC (20625102), “111” programe of Ministry of Education and Science and Technology Bureau of Jilin Province.

PY - 2009/1

Y1 - 2009/1

N2 - A novel zinc diphosphonate, Zn[HO3PCH2(C6H4)CH2PO3H] (1) was synthesized from tetraethyl para-xylylenediphosphonate, Et2O3PCH2C6H4CH2PO3Et2, and Zn (AcO)2·2H2O under solvothermal conditions. The structure of compound 1 was determined by single-crystal X-ray diffraction, which reveals that the structure crystallizes in the monoclinic space group C2/c (No. 15), with a = 22.4844(19) Å, b = 6.4361(5) Å, c = 8.1194(7) Å, β = 102.595(2)°, V = 1146.70(16) Å3, T = 298(2) K, Z = 8. The novel three-dimensional (3D) construction is simply built up from linear inorganic chains of corner-sharing four-rings of tetrahedral [ZnO4] and [PO3C] which connected adjacent chains by the organophosphorus ligand para-xylylenediphosphonate. The framework has 10 Å × 4 Å (containing the van der Waals radii of atoms) channels running along the b-axis.

AB - A novel zinc diphosphonate, Zn[HO3PCH2(C6H4)CH2PO3H] (1) was synthesized from tetraethyl para-xylylenediphosphonate, Et2O3PCH2C6H4CH2PO3Et2, and Zn (AcO)2·2H2O under solvothermal conditions. The structure of compound 1 was determined by single-crystal X-ray diffraction, which reveals that the structure crystallizes in the monoclinic space group C2/c (No. 15), with a = 22.4844(19) Å, b = 6.4361(5) Å, c = 8.1194(7) Å, β = 102.595(2)°, V = 1146.70(16) Å3, T = 298(2) K, Z = 8. The novel three-dimensional (3D) construction is simply built up from linear inorganic chains of corner-sharing four-rings of tetrahedral [ZnO4] and [PO3C] which connected adjacent chains by the organophosphorus ligand para-xylylenediphosphonate. The framework has 10 Å × 4 Å (containing the van der Waals radii of atoms) channels running along the b-axis.

KW - Diphosphonate

KW - Open-framework

KW - Organic-inorganic hybrid

KW - Solvothermal

UR - https://www.scopus.com/pages/publications/58049118325

U2 - 10.1016/j.solidstatesciences.2008.06.004

DO - 10.1016/j.solidstatesciences.2008.06.004

M3 - Article

AN - SCOPUS:58049118325

SN - 1293-2558

VL - 11

SP - 68

EP - 71

JO - Solid State Sciences

JF - Solid State Sciences

IS - 1