Syntheses and structures of silver(I) complexes with new tripodal ligand containing propanenitrile and imidazolyl groups

Kai Cai; Yuan Yuan Wang; Xin Zhou; Zhao Peng Qi; Peng Wang; Zhi Su; Wei Yin Sun

Syntheses and structures of silver(I) complexes with new tripodal ligand containing propanenitrile and imidazolyl groups

Kai Cai
, Yuan Yuan Wang
, Xin Zhou
, Zhao Peng Qi
, Peng Wang
, Zhi Su
, Wei Yin Sun

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

New complexes {[AgL]X}_n(X=BF₄^-, 1a; X=ClO₄^-, 1b) and {[Ag(L)₂]ClO₄}_n(2) were synthesized by the reactions of corresponding silver(I) salt with new tripodal ligand 3, 3'-[3-(1H-imidazol-1-yl) propylazanediyl] dipropanenitrile(L) under ligand to metal ratio of 1:1 and 2:1, respectively, and their structures were determined by single crystal X-ray diffraction and electrospray mass spectrometry. Complexes 1a and 1b have one-dimensional(1D) chain structure while complex 2 is mononuclear. The results show that the metal to ligand ratio has subtle influence on the structure of the complexes.

Original language	English
Pages (from-to)	2193-2197
Number of pages	5
Journal	Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
Volume	32
Issue number	9
State	Published - Sep 2011
Externally published	Yes

Keywords

Crystal structure
Electrospray mass spectrometry
Silver(I) complex
Tripodal ligand

Cite this

@article{0b0bd5bbb2094843a5b27fb8cc6315f0,

title = "Syntheses and structures of silver(I) complexes with new tripodal ligand containing propanenitrile and imidazolyl groups",

abstract = "New complexes \{[AgL]X\}n(X=BF4-, 1a; X=ClO4-, 1b) and \{[Ag(L)2]ClO4\}n(2) were synthesized by the reactions of corresponding silver(I) salt with new tripodal ligand 3, 3'-[3-(1H-imidazol-1-yl) propylazanediyl] dipropanenitrile(L) under ligand to metal ratio of 1:1 and 2:1, respectively, and their structures were determined by single crystal X-ray diffraction and electrospray mass spectrometry. Complexes 1a and 1b have one-dimensional(1D) chain structure while complex 2 is mononuclear. The results show that the metal to ligand ratio has subtle influence on the structure of the complexes.",

keywords = "Crystal structure, Electrospray mass spectrometry, Silver(I) complex, Tripodal ligand",

author = "Kai Cai and Wang, \{Yuan Yuan\} and Xin Zhou and Qi, \{Zhao Peng\} and Peng Wang and Zhi Su and Sun, \{Wei Yin\}",

year = "2011",

month = sep,

language = "English",

volume = "32",

pages = "2193--2197",

journal = "Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "9",

}

TY - JOUR

T1 - Syntheses and structures of silver(I) complexes with new tripodal ligand containing propanenitrile and imidazolyl groups

AU - Cai, Kai

AU - Wang, Yuan Yuan

AU - Zhou, Xin

AU - Qi, Zhao Peng

AU - Wang, Peng

AU - Su, Zhi

AU - Sun, Wei Yin

PY - 2011/9

Y1 - 2011/9

N2 - New complexes {[AgL]X}n(X=BF4-, 1a; X=ClO4-, 1b) and {[Ag(L)2]ClO4}n(2) were synthesized by the reactions of corresponding silver(I) salt with new tripodal ligand 3, 3'-[3-(1H-imidazol-1-yl) propylazanediyl] dipropanenitrile(L) under ligand to metal ratio of 1:1 and 2:1, respectively, and their structures were determined by single crystal X-ray diffraction and electrospray mass spectrometry. Complexes 1a and 1b have one-dimensional(1D) chain structure while complex 2 is mononuclear. The results show that the metal to ligand ratio has subtle influence on the structure of the complexes.

AB - New complexes {[AgL]X}n(X=BF4-, 1a; X=ClO4-, 1b) and {[Ag(L)2]ClO4}n(2) were synthesized by the reactions of corresponding silver(I) salt with new tripodal ligand 3, 3'-[3-(1H-imidazol-1-yl) propylazanediyl] dipropanenitrile(L) under ligand to metal ratio of 1:1 and 2:1, respectively, and their structures were determined by single crystal X-ray diffraction and electrospray mass spectrometry. Complexes 1a and 1b have one-dimensional(1D) chain structure while complex 2 is mononuclear. The results show that the metal to ligand ratio has subtle influence on the structure of the complexes.

KW - Crystal structure

KW - Electrospray mass spectrometry

KW - Silver(I) complex

KW - Tripodal ligand

UR - https://www.scopus.com/pages/publications/80355131578

M3 - Article

AN - SCOPUS:80355131578

SN - 0251-0790

VL - 32

SP - 2193

EP - 2197

JO - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

JF - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

IS - 9

ER -

Syntheses and structures of silver(I) complexes with new tripodal ligand containing propanenitrile and imidazolyl groups

Abstract

Keywords

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