Syntheses and structures of silver(I) complexes with new tripodal ligand containing propanenitrile and imidazolyl groups

Kai Cai; Yuan Yuan Wang; Xin Zhou; Zhao Peng Qi; Peng Wang; Zhi Su; Wei Yin Sun

Syntheses and structures of silver(I) complexes with new tripodal ligand containing propanenitrile and imidazolyl groups

Kai Cai, Yuan Yuan Wang, Xin Zhou, Zhao Peng Qi, Peng Wang, Zhi Su, Wei Yin Sun

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

New complexes {[AgL]X}_n(X=BF₄^-, 1a; X=ClO₄^-, 1b) and {[Ag(L)₂]ClO₄}_n(2) were synthesized by the reactions of corresponding silver(I) salt with new tripodal ligand 3, 3'-[3-(1H-imidazol-1-yl) propylazanediyl] dipropanenitrile(L) under ligand to metal ratio of 1:1 and 2:1, respectively, and their structures were determined by single crystal X-ray diffraction and electrospray mass spectrometry. Complexes 1a and 1b have one-dimensional(1D) chain structure while complex 2 is mononuclear. The results show that the metal to ligand ratio has subtle influence on the structure of the complexes.

Original language	English
Pages (from-to)	2193-2197
Number of pages	5
Journal	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume	32
Issue number	9
State	Published - Sep 2011
Externally published	Yes

Keywords

Crystal structure
Electrospray mass spectrometry
Silver(I) complex
Tripodal ligand

Cite this

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title = "Syntheses and structures of silver(I) complexes with new tripodal ligand containing propanenitrile and imidazolyl groups",

abstract = "New complexes {[AgL]X}n(X=BF4-, 1a; X=ClO4-, 1b) and {[Ag(L)2]ClO4}n(2) were synthesized by the reactions of corresponding silver(I) salt with new tripodal ligand 3, 3'-[3-(1H-imidazol-1-yl) propylazanediyl] dipropanenitrile(L) under ligand to metal ratio of 1:1 and 2:1, respectively, and their structures were determined by single crystal X-ray diffraction and electrospray mass spectrometry. Complexes 1a and 1b have one-dimensional(1D) chain structure while complex 2 is mononuclear. The results show that the metal to ligand ratio has subtle influence on the structure of the complexes.",

keywords = "Crystal structure, Electrospray mass spectrometry, Silver(I) complex, Tripodal ligand",

author = "Kai Cai and Wang, {Yuan Yuan} and Xin Zhou and Qi, {Zhao Peng} and Peng Wang and Zhi Su and Sun, {Wei Yin}",

year = "2011",

month = sep,

language = "English",

volume = "32",

pages = "2193--2197",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

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publisher = "Higher Education Press",

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TY - JOUR

T1 - Syntheses and structures of silver(I) complexes with new tripodal ligand containing propanenitrile and imidazolyl groups

AU - Cai, Kai

AU - Wang, Yuan Yuan

AU - Zhou, Xin

AU - Qi, Zhao Peng

AU - Wang, Peng

AU - Su, Zhi

AU - Sun, Wei Yin

PY - 2011/9

Y1 - 2011/9

N2 - New complexes {[AgL]X}n(X=BF4-, 1a; X=ClO4-, 1b) and {[Ag(L)2]ClO4}n(2) were synthesized by the reactions of corresponding silver(I) salt with new tripodal ligand 3, 3'-[3-(1H-imidazol-1-yl) propylazanediyl] dipropanenitrile(L) under ligand to metal ratio of 1:1 and 2:1, respectively, and their structures were determined by single crystal X-ray diffraction and electrospray mass spectrometry. Complexes 1a and 1b have one-dimensional(1D) chain structure while complex 2 is mononuclear. The results show that the metal to ligand ratio has subtle influence on the structure of the complexes.

AB - New complexes {[AgL]X}n(X=BF4-, 1a; X=ClO4-, 1b) and {[Ag(L)2]ClO4}n(2) were synthesized by the reactions of corresponding silver(I) salt with new tripodal ligand 3, 3'-[3-(1H-imidazol-1-yl) propylazanediyl] dipropanenitrile(L) under ligand to metal ratio of 1:1 and 2:1, respectively, and their structures were determined by single crystal X-ray diffraction and electrospray mass spectrometry. Complexes 1a and 1b have one-dimensional(1D) chain structure while complex 2 is mononuclear. The results show that the metal to ligand ratio has subtle influence on the structure of the complexes.

KW - Crystal structure

KW - Electrospray mass spectrometry

KW - Silver(I) complex

KW - Tripodal ligand

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M3 - Article

AN - SCOPUS:80355131578

SN - 0251-0790

VL - 32

SP - 2193

EP - 2197

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 9

ER -

Syntheses and structures of silver(I) complexes with new tripodal ligand containing propanenitrile and imidazolyl groups

Abstract

Keywords

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