Syntheses and spectroscopic studies of mono(cyclopentadienyl) titanium(IV) and bis(cyclopentadienyl)titanium(IV)/zirconium(IV) derivatives with acetylferrocenyl Schiff bases

S. K. Srivastava, B. K. Srivastava, S. K. Sengupta, O. P. Pandey

Research output: Contribution to journalArticlepeer-review

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Abstract

The reactions of Schiff bases (L), derived by the condensation of acetylferrocene with ethylenediamine, o-phenylenediamine, 4-methyl-o-phenylenediamine, 1,8-diaminonaphthalene and 2,6-diaminopyridine, with bis(cyclopentadienyl)titanium(IV)/ zirconium(IV) dichloride and mono (cyclopentadienyl)titanium(IV) trichloride have been studied and complexes of the types [Cp2M(L)Cl]Cl (M=Ti(IV) or Zr(IV)), [CpTiCl3(L)] have been isolated and characterized by elemental analysis, electrical conductance, magnetic moment and spectral (electrical, infrared, 1H NMR) data.

Original languageEnglish
Pages (from-to)544-546
Number of pages3
JournalIndian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume37
Issue number6
StatePublished - 1998
Externally publishedYes

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