TY - JOUR
T1 - Syntheses and spectroscopic studies of mono- and dicyclopentadienyl titanium (IV)/zirconium (IV) derivatives with S-alkyl-β-N-(acetylferrocenyl) methylene dithiocarbazates
AU - Srivastava, B. K.
AU - Srivastava, S. K.
AU - Pandey, O. P.
AU - Sengupta, S. K.
PY - 1996/1
Y1 - 1996/1
N2 - The reactions of dicyclopentadienyl titanium (IV)/ zirconium (IV) dichloride and monocyclopentadienyl titanium (IV) trichloride with thio-Schiff bases (LH), derived by the condensation of S-methyl/ethyl/propyl dithiocarbazic acid and acetylferrocene, have been carried out under inert atmosphere and anhydrous conditions in different stoichiometric ratios. Complexes of the types Cp2M(L)Cl, CpM(L)2Cl (M=Ti(IV) or Zr(IV)), CpTi(L)Cl2, CpTi(L)2Cl are synthesised and characterized by elemental analysis, electrical conductance, magnetic moment and spectral (electronic, infrared, 1H NMR) data.
AB - The reactions of dicyclopentadienyl titanium (IV)/ zirconium (IV) dichloride and monocyclopentadienyl titanium (IV) trichloride with thio-Schiff bases (LH), derived by the condensation of S-methyl/ethyl/propyl dithiocarbazic acid and acetylferrocene, have been carried out under inert atmosphere and anhydrous conditions in different stoichiometric ratios. Complexes of the types Cp2M(L)Cl, CpM(L)2Cl (M=Ti(IV) or Zr(IV)), CpTi(L)Cl2, CpTi(L)2Cl are synthesised and characterized by elemental analysis, electrical conductance, magnetic moment and spectral (electronic, infrared, 1H NMR) data.
UR - http://www.scopus.com/inward/record.url?scp=2842512485&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:2842512485
SN - 0376-4710
VL - 35
SP - 57
EP - 59
JO - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
JF - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
IS - 1
ER -