Syntheses and spectroscopic studies of mono- and dicyclopentadienyl titanium (IV)/zirconium (IV) derivatives with S-alkyl-β-N-(acetylferrocenyl) methylene dithiocarbazates

B. K. Srivastava, S. K. Srivastava, O. P. Pandey, S. K. Sengupta

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Abstract

The reactions of dicyclopentadienyl titanium (IV)/ zirconium (IV) dichloride and monocyclopentadienyl titanium (IV) trichloride with thio-Schiff bases (LH), derived by the condensation of S-methyl/ethyl/propyl dithiocarbazic acid and acetylferrocene, have been carried out under inert atmosphere and anhydrous conditions in different stoichiometric ratios. Complexes of the types Cp2M(L)Cl, CpM(L)2Cl (M=Ti(IV) or Zr(IV)), CpTi(L)Cl2, CpTi(L)2Cl are synthesised and characterized by elemental analysis, electrical conductance, magnetic moment and spectral (electronic, infrared, 1H NMR) data.

Original languageEnglish
Pages (from-to)57-59
Number of pages3
JournalIndian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume35
Issue number1
StatePublished - Jan 1996
Externally publishedYes

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