Silver-catalyzed radical carbofluorination of unactivated alkenes with acetic acid in aqueous solution

He Chen; Lin Zhu; Chaozhong Li

doi:10.1039/c6qo00854b

Silver-catalyzed radical carbofluorination of unactivated alkenes with acetic acid in aqueous solution

He Chen, Lin Zhu, Chaozhong Li

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

The AgNO₃-catalyzed reactions of unactivated alkenes with acetic acid and Selectfluor reagent in aqueous solution afforded the corresponding γ-fluorinated carboxylic acids under mild conditions. Carbofluorination was not only efficient and regioselective, but also enjoyed a wide functional group compatibility.

Original language	English
Pages (from-to)	565-568
Number of pages	4
Journal	Organic Chemistry Frontiers
Volume	4
Issue number	4
DOIs	https://doi.org/10.1039/c6qo00854b
State	Published - Apr 2017
Externally published	Yes

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title = "Silver-catalyzed radical carbofluorination of unactivated alkenes with acetic acid in aqueous solution",

abstract = "The AgNO3-catalyzed reactions of unactivated alkenes with acetic acid and Selectfluor reagent in aqueous solution afforded the corresponding γ-fluorinated carboxylic acids under mild conditions. Carbofluorination was not only efficient and regioselective, but also enjoyed a wide functional group compatibility.",

author = "He Chen and Lin Zhu and Chaozhong Li",

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AU - Chen, He

AU - Zhu, Lin

AU - Li, Chaozhong

N1 - Publisher Copyright: © the Partner Organisations 2017.

PY - 2017/4

Y1 - 2017/4

N2 - The AgNO3-catalyzed reactions of unactivated alkenes with acetic acid and Selectfluor reagent in aqueous solution afforded the corresponding γ-fluorinated carboxylic acids under mild conditions. Carbofluorination was not only efficient and regioselective, but also enjoyed a wide functional group compatibility.

AB - The AgNO3-catalyzed reactions of unactivated alkenes with acetic acid and Selectfluor reagent in aqueous solution afforded the corresponding γ-fluorinated carboxylic acids under mild conditions. Carbofluorination was not only efficient and regioselective, but also enjoyed a wide functional group compatibility.

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U2 - 10.1039/c6qo00854b

DO - 10.1039/c6qo00854b

M3 - Article

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SP - 565

EP - 568

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 4

ER -

Silver-catalyzed radical carbofluorination of unactivated alkenes with acetic acid in aqueous solution

Abstract

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