Abstract
A new series of hydrogen bonding-driven heterodimers have been self-assembled in chloroform from hydrazide-based monomers. Additional intermolecular donor-acceptor interaction between the electron-rich bis(p-phenylene)-34-crown-10 unit and the electron-deficient naphthalene diimide unit has been utilized to increase the stability of the dimmers, and pronounced cooperativity of the two discrete non-covalent forces to stabilize the dimer has been revealed by the quantitative 1H (2D) NMR and UV-Vis experiments.
| Original language | English |
|---|---|
| Pages (from-to) | 1200-1208 |
| Number of pages | 9 |
| Journal | Chinese Journal of Chemistry |
| Volume | 24 |
| Issue number | 9 |
| DOIs | |
| State | Published - Sep 2006 |
| Externally published | Yes |
Keywords
- Donor-acceptor interaction
- Heterodimer
- Hydrazide
- Hydrogen bonding
- Self-assembly