The reactions of equimolar amounts of monoicyclopentadienyl)-titanium(IV) trichloride with different Schiff bases in anhydrous dichloromethane have yielded complexes of the types (C5K5’TiCl5dB and (C5E5TlCl.UrB1) (where 33 = schiff bases derived from carbohydrazide and benzaldehyde, [formula omitted]-nitrobenzaldehyde, [formula omitted]-nitrobenzaldehyde, acetophenone, [formula omitted]-hydroxyacetophenone, anisaldehyde, cinnamaldehyde and vanilline; 33’Rg = achiff bases derived from rlcarbohydrazide and salicylaldehyde, [formula omitted]-hydroxyacetophenone). A study of the COndUCtdnCe, mdgnetic susceptibility, electronic, infrared and 11 n.m.r. spectra oP these complexes in addition to the elemental analyses has been carried out t o elucidate the probable structure of these derivatives. type b3 act as neutral t ridentate chelzting agents, whereas those of type S'13'H2 act as dibasic, tetradentate chelating agents.
|Number of pages||14|
|Journal||Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry|
|State||Published - 1 Jan 1983|