TY - JOUR
T1 - Schiff Base Derivatives of Mono(cyclopentadienyl)titanium(IV)
AU - Pandey, O. P.
AU - Sengupta, S. K.
AU - Tripathi, B. C.
N1 - Funding Information:
ACKNOWL@GEM"ET The authors are thankful t o the Indian National Science Academy for financial assistance.
PY - 1983/1/1
Y1 - 1983/1/1
N2 - The reactions of equimolar amounts of monoicyclopentadienyl)-titanium(IV) trichloride with different Schiff bases in anhydrous dichloromethane have yielded complexes of the types (C5K5’TiCl5dB and (C5E5TlCl.UrB1) (where 33 = schiff bases derived from carbohydrazide and benzaldehyde, [formula omitted]-nitrobenzaldehyde, [formula omitted]-nitrobenzaldehyde, acetophenone, [formula omitted]-hydroxyacetophenone, anisaldehyde, cinnamaldehyde and vanilline; 33’Rg = achiff bases derived from rlcarbohydrazide and salicylaldehyde, [formula omitted]-hydroxyacetophenone). A study of the COndUCtdnCe, mdgnetic susceptibility, electronic, infrared and 11 n.m.r. spectra oP these complexes in addition to the elemental analyses has been carried out t o elucidate the probable structure of these derivatives. type b3 act as neutral t ridentate chelzting agents, whereas those of type S'13'H2 act as dibasic, tetradentate chelating agents.
AB - The reactions of equimolar amounts of monoicyclopentadienyl)-titanium(IV) trichloride with different Schiff bases in anhydrous dichloromethane have yielded complexes of the types (C5K5’TiCl5dB and (C5E5TlCl.UrB1) (where 33 = schiff bases derived from carbohydrazide and benzaldehyde, [formula omitted]-nitrobenzaldehyde, [formula omitted]-nitrobenzaldehyde, acetophenone, [formula omitted]-hydroxyacetophenone, anisaldehyde, cinnamaldehyde and vanilline; 33’Rg = achiff bases derived from rlcarbohydrazide and salicylaldehyde, [formula omitted]-hydroxyacetophenone). A study of the COndUCtdnCe, mdgnetic susceptibility, electronic, infrared and 11 n.m.r. spectra oP these complexes in addition to the elemental analyses has been carried out t o elucidate the probable structure of these derivatives. type b3 act as neutral t ridentate chelzting agents, whereas those of type S'13'H2 act as dibasic, tetradentate chelating agents.
UR - http://www.scopus.com/inward/record.url?scp=84963457474&partnerID=8YFLogxK
U2 - 10.1080/00945718308059349
DO - 10.1080/00945718308059349
M3 - Article
AN - SCOPUS:84963457474
SN - 0094-5714
VL - 13
SP - 867
EP - 880
JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
IS - 7
ER -