Review on application of isotope tracing technique in the investigation of synthetic mechanism and biodegradation of HMX

Qing Xia Li; Peng Wang; Zi Hui Meng; Wen Jun Meng; Zhong Liang Lou; Hong Yan Song

Review on application of isotope tracing technique in the investigation of synthetic mechanism and biodegradation of HMX

Qing Xia Li, Peng Wang, Zi Hui Meng, Wen Jun Meng, Zhong Liang Lou, Hong Yan Song

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The synthesis of isotope labeled cyclotetramethylenetetramine (HMX) and its precursor, and the application of isotope tracing technique in the synthesis of HMX by acetic anhydride method and non-acetic anhydride method were summarized. The application of isotope tracing technology in the biodegradation process of energetic contaminants were also introduced. The study shows that HMX prepared from the acetic anhydride method tends to restructuring mechanism; HMX prepared from the TAT and DADN method is more inclined to the step-by-step degradation mechanism. HMX-¹⁴C can be used for the quantitative and qualitative analysis of biological degradation products accurately.

Original language	English
Pages (from-to)	369-373
Number of pages	5
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	17
Issue number	3
State	Published - Jun 2009
Externally published	Yes

Keywords

Analytical chemistry
Biodegradation
Cyclotetramethylenetetramine (HMX)
Isotope tracing technology
Reaction mechanism

Cite this

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title = "Review on application of isotope tracing technique in the investigation of synthetic mechanism and biodegradation of HMX",

abstract = "The synthesis of isotope labeled cyclotetramethylenetetramine (HMX) and its precursor, and the application of isotope tracing technique in the synthesis of HMX by acetic anhydride method and non-acetic anhydride method were summarized. The application of isotope tracing technology in the biodegradation process of energetic contaminants were also introduced. The study shows that HMX prepared from the acetic anhydride method tends to restructuring mechanism; HMX prepared from the TAT and DADN method is more inclined to the step-by-step degradation mechanism. HMX-14C can be used for the quantitative and qualitative analysis of biological degradation products accurately.",

keywords = "Analytical chemistry, Biodegradation, Cyclotetramethylenetetramine (HMX), Isotope tracing technology, Reaction mechanism",

author = "Li, {Qing Xia} and Peng Wang and Meng, {Zi Hui} and Meng, {Wen Jun} and Lou, {Zhong Liang} and Song, {Hong Yan}",

year = "2009",

month = jun,

language = "English",

volume = "17",

pages = "369--373",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Chinese Academy of Engineering Physics",

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TY - JOUR

T1 - Review on application of isotope tracing technique in the investigation of synthetic mechanism and biodegradation of HMX

AU - Li, Qing Xia

AU - Wang, Peng

AU - Meng, Zi Hui

AU - Meng, Wen Jun

AU - Lou, Zhong Liang

AU - Song, Hong Yan

PY - 2009/6

Y1 - 2009/6

N2 - The synthesis of isotope labeled cyclotetramethylenetetramine (HMX) and its precursor, and the application of isotope tracing technique in the synthesis of HMX by acetic anhydride method and non-acetic anhydride method were summarized. The application of isotope tracing technology in the biodegradation process of energetic contaminants were also introduced. The study shows that HMX prepared from the acetic anhydride method tends to restructuring mechanism; HMX prepared from the TAT and DADN method is more inclined to the step-by-step degradation mechanism. HMX-14C can be used for the quantitative and qualitative analysis of biological degradation products accurately.

AB - The synthesis of isotope labeled cyclotetramethylenetetramine (HMX) and its precursor, and the application of isotope tracing technique in the synthesis of HMX by acetic anhydride method and non-acetic anhydride method were summarized. The application of isotope tracing technology in the biodegradation process of energetic contaminants were also introduced. The study shows that HMX prepared from the acetic anhydride method tends to restructuring mechanism; HMX prepared from the TAT and DADN method is more inclined to the step-by-step degradation mechanism. HMX-14C can be used for the quantitative and qualitative analysis of biological degradation products accurately.

KW - Analytical chemistry

KW - Biodegradation

KW - Cyclotetramethylenetetramine (HMX)

KW - Isotope tracing technology

KW - Reaction mechanism

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M3 - Article

AN - SCOPUS:68049103117

SN - 1006-9941

VL - 17

SP - 369

EP - 373

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 3

ER -

Review on application of isotope tracing technique in the investigation of synthetic mechanism and biodegradation of HMX

Abstract

Keywords

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