Reactions of hafnium(iv) isopropoxide isopropanolate with mercapto triazoles

Om Prakash Pandey

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The reactions of hafnium(IV) isopropoxide isopropanolate with 3-methyl-4-amino-S~triazol-5-thiol, 3-ethyl-4-amino-S-triazol-5-thiol and also with Schiff bases derived from amino triazoles with benzaldehyde, acetophenone, salicylaldehyde or o-hydroxyacetophenone have been carried out in different molar ratios l:n (n = 1 to 4) in refluxing benzene. The products of the types [Hf(OPr2) 4-n (L)n] (n = 1, 2 or 3), [Hf(OPri)4-n(L'>n] (n = 1 or 2), [Hf(OPri)4-2n(L)n] (n = 1 or 2) (LH = 3-methyl/ethyl-4-amino-S-triazol-5-thiol; L'H = Schiff bases derived by condensation of LH with benzaldehyde and acetophenone; L “H2= Schiff bases derived by condensation of LH with salicylaldehyde or o-hydroxyacetophenone) have been isolated and characterized on the basis of elemental analysis, electrical conductance magnetic moment and spectral (electronic, infrared and lH n.m.r.) data.

Original languageEnglish
Pages (from-to)575-591
Number of pages17
JournalSynthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume18
Issue number6
DOIs
StatePublished - 1 Jan 1988
Externally publishedYes

Fingerprint

Dive into the research topics of 'Reactions of hafnium(iv) isopropoxide isopropanolate with mercapto triazoles'. Together they form a unique fingerprint.

Cite this