TY - JOUR
T1 - Reaction mechanism for the formation of 1,3-ditertiobutyl-5,5- Dinitrohexahydropyrimidine
AU - Li, Qingxia
AU - Wang, Peng
AU - Meng, Wenjun
AU - Meng, Zihui
AU - Lou, Zhongliang
AU - Song, Hongyan
AU - Qin, Guangming
AU - Ge, Zhongxue
AU - Wang, Bozhou
PY - 2010/3
Y1 - 2010/3
N2 - The key precursor of the energetic plasticizer 1,3,5,5- tetranitrohexahydropyrirnidine is 1,3-ditertiobutyl-5,5- dinitrohexahydropyrimidine, which was synthesized from 2,2-dinitropropane-1,3- diol, formaldehyde and tert-butylamine via Mannich reaction. A stable intermediate N-benzyl-2,2-dinitroethylamine was obtained, and isotope tracing experiment was employed to elucidate the reaction process, and finally a synthetic mechanism for 1,3-ditertiobutyl-5,5-dinitrohexahydropyrimidine was proposed.
AB - The key precursor of the energetic plasticizer 1,3,5,5- tetranitrohexahydropyrirnidine is 1,3-ditertiobutyl-5,5- dinitrohexahydropyrimidine, which was synthesized from 2,2-dinitropropane-1,3- diol, formaldehyde and tert-butylamine via Mannich reaction. A stable intermediate N-benzyl-2,2-dinitroethylamine was obtained, and isotope tracing experiment was employed to elucidate the reaction process, and finally a synthetic mechanism for 1,3-ditertiobutyl-5,5-dinitrohexahydropyrimidine was proposed.
KW - 1,3-ditertiobutyl-5,5- dinitrohexahydropyrimidine
KW - 2,2-dinitropropane-1,3-diol
KW - Mannich reaction
KW - Synthetic mechanism
UR - http://www.scopus.com/inward/record.url?scp=77953588067&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:77953588067
SN - 0253-2786
VL - 30
SP - 409
EP - 413
JO - Chinese Journal of Organic Chemistry
JF - Chinese Journal of Organic Chemistry
IS - 3
ER -