Insights into the induced ultrafast electron delocalization in Fe(CO) 5 using dark channel fluorescence yield X-ray absorption

Matthias Bauer; Tom Stalinski; Emad F. Aziz

doi:10.1002/cphc.201100243

Insights into the induced ultrafast electron delocalization in Fe(CO) ₅ using dark channel fluorescence yield X-ray absorption

Matthias Bauer, Tom Stalinski, Emad F. Aziz

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Well-coordinated: L_2,3-edge X-ray absorption measurements of Fe(CO)₅, carried out for the first time in solution, are discussed (see picture). Using the dark channel fluorescence yield technique, ultrafast delocalization processes on the femtosecond time-scale yield new insights into the electronic structure.

Original language	English
Pages (from-to)	2088-2091
Number of pages	4
Journal	ChemPhysChem
Volume	12
Issue number	11
DOIs	https://doi.org/10.1002/cphc.201100243
State	Published - 1 Aug 2011
Externally published	Yes

Keywords

X-ray absorption spectroscopy
computational chemistry
electronic structure
ultra-fast dynamics

Access to Document

10.1002/cphc.201100243

Cite this

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abstract = "Well-coordinated: L2,3-edge X-ray absorption measurements of Fe(CO)5, carried out for the first time in solution, are discussed (see picture). Using the dark channel fluorescence yield technique, ultrafast delocalization processes on the femtosecond time-scale yield new insights into the electronic structure.",

keywords = "X-ray absorption spectroscopy, computational chemistry, electronic structure, ultra-fast dynamics",

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AU - Aziz, Emad F.

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AB - Well-coordinated: L2,3-edge X-ray absorption measurements of Fe(CO)5, carried out for the first time in solution, are discussed (see picture). Using the dark channel fluorescence yield technique, ultrafast delocalization processes on the femtosecond time-scale yield new insights into the electronic structure.

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KW - electronic structure

KW - ultra-fast dynamics

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