Insights into the induced ultrafast electron delocalization in Fe(CO) 5 using dark channel fluorescence yield X-ray absorption

Matthias Bauer, Tom Stalinski, Emad F. Aziz

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

Well-coordinated: L2,3-edge X-ray absorption measurements of Fe(CO)5, carried out for the first time in solution, are discussed (see picture). Using the dark channel fluorescence yield technique, ultrafast delocalization processes on the femtosecond time-scale yield new insights into the electronic structure.

Original languageEnglish
Pages (from-to)2088-2091
Number of pages4
JournalChemPhysChem
Volume12
Issue number11
DOIs
StatePublished - 1 Aug 2011
Externally publishedYes

Keywords

  • X-ray absorption spectroscopy
  • computational chemistry
  • electronic structure
  • ultra-fast dynamics

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