Influence of CdO and gamma irradiation on the infrared absorption spectra of borosilicate glass

Ravneet Kaur; Surinder Singh; O. P. Pandey

doi:10.1016/j.molstruc.2013.06.072

Influence of CdO and gamma irradiation on the infrared absorption spectra of borosilicate glass

Ravneet Kaur, Surinder Singh, O. P. Pandey

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

The effect of modifier CdO and gamma irradiation in the dose range of 0.1-60 kGy on the structure of sodium borosilicate glasses is investigated by preparing a series of glasses with compositions xCdO-15Na₂O-(70-x) B₂O₃-15SiO₂; where x= 5, 10, 15, 20, 25 (mol%) by conventional melt quenching technique. FTIR structural studies were carried out on the glass system before and after gamma irradiation. The infrared absorption studies revealed that structure of glass network consists of [BO ₃], [BO₄], [SiO₄] and [B-O-Cd] linkages. The modifying action of cadmium oxide on the glass composition is also studied. It is observed that increased gamma radiation dose causes the B-O bond to break and form non-bridging oxygens (NBOs).

Original language	English
Pages (from-to)	409-413
Number of pages	5
Journal	Journal of Molecular Structure
Volume	1049
DOIs	https://doi.org/10.1016/j.molstruc.2013.06.072
State	Published - 2013
Externally published	Yes

Keywords

Borosilicate glasses
CdO
FT-IR
Gamma irradiation
NBOs
Radiation effects

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10.1016/j.molstruc.2013.06.072

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@article{a137ff1c6d0748e6849f438bef2325e0,

title = "Influence of CdO and gamma irradiation on the infrared absorption spectra of borosilicate glass",

abstract = "The effect of modifier CdO and gamma irradiation in the dose range of 0.1-60 kGy on the structure of sodium borosilicate glasses is investigated by preparing a series of glasses with compositions xCdO-15Na2O-(70-x) B2O3-15SiO2; where x= 5, 10, 15, 20, 25 (mol%) by conventional melt quenching technique. FTIR structural studies were carried out on the glass system before and after gamma irradiation. The infrared absorption studies revealed that structure of glass network consists of [BO 3], [BO4], [SiO4] and [B-O-Cd] linkages. The modifying action of cadmium oxide on the glass composition is also studied. It is observed that increased gamma radiation dose causes the B-O bond to break and form non-bridging oxygens (NBOs).",

keywords = "Borosilicate glasses, CdO, FT-IR, Gamma irradiation, NBOs, Radiation effects",

author = "Ravneet Kaur and Surinder Singh and Pandey, {O. P.}",

note = "Funding Information: The authors are thankful to IUAC, New Delhi for providing the financial assistance and necessary experimental facilities for the completion of this work.",

year = "2013",

doi = "10.1016/j.molstruc.2013.06.072",

language = "English",

volume = "1049",

pages = "409--413",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Influence of CdO and gamma irradiation on the infrared absorption spectra of borosilicate glass

AU - Kaur, Ravneet

AU - Singh, Surinder

AU - Pandey, O. P.

N1 - Funding Information: The authors are thankful to IUAC, New Delhi for providing the financial assistance and necessary experimental facilities for the completion of this work.

PY - 2013

Y1 - 2013

N2 - The effect of modifier CdO and gamma irradiation in the dose range of 0.1-60 kGy on the structure of sodium borosilicate glasses is investigated by preparing a series of glasses with compositions xCdO-15Na2O-(70-x) B2O3-15SiO2; where x= 5, 10, 15, 20, 25 (mol%) by conventional melt quenching technique. FTIR structural studies were carried out on the glass system before and after gamma irradiation. The infrared absorption studies revealed that structure of glass network consists of [BO 3], [BO4], [SiO4] and [B-O-Cd] linkages. The modifying action of cadmium oxide on the glass composition is also studied. It is observed that increased gamma radiation dose causes the B-O bond to break and form non-bridging oxygens (NBOs).

AB - The effect of modifier CdO and gamma irradiation in the dose range of 0.1-60 kGy on the structure of sodium borosilicate glasses is investigated by preparing a series of glasses with compositions xCdO-15Na2O-(70-x) B2O3-15SiO2; where x= 5, 10, 15, 20, 25 (mol%) by conventional melt quenching technique. FTIR structural studies were carried out on the glass system before and after gamma irradiation. The infrared absorption studies revealed that structure of glass network consists of [BO 3], [BO4], [SiO4] and [B-O-Cd] linkages. The modifying action of cadmium oxide on the glass composition is also studied. It is observed that increased gamma radiation dose causes the B-O bond to break and form non-bridging oxygens (NBOs).

KW - Borosilicate glasses

KW - CdO

KW - FT-IR

KW - Gamma irradiation

KW - NBOs

KW - Radiation effects

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U2 - 10.1016/j.molstruc.2013.06.072

DO - 10.1016/j.molstruc.2013.06.072

M3 - Article

AN - SCOPUS:84885163227

SN - 0022-2860

VL - 1049

SP - 409

EP - 413

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -

Influence of CdO and gamma irradiation on the infrared absorption spectra of borosilicate glass

Abstract

Keywords

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