Hydrovinylation and related reactions: New protocols and control elements in search of greater synthetic efficiency and selectivity

T. V. RajanBabu; Nobuyoshi Nomura; Jian Jin; Branko Radetich; Haengsoon Park; Malay Nandi

doi:10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4

Hydrovinylation and related reactions: New protocols and control elements in search of greater synthetic efficiency and selectivity

T. V. RajanBabu
, Nobuyoshi Nomura
, Jian Jin
, Branko Radetich
, Haengsoon Park
, Malay Nandi

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

New protocols for highly selective and nearly quantitative heterodimerization of ethylene or propylene with various functionalized vinylarenes are described. Under these conditions, which are compatible with a wide variety of functional groups, cylization of 1,6-dienes and hydrovinylation of norbornenes can also be accomplished. Also presented are possible strategies for stereo-chemical control, including a crucial role for hemilabile ligands in enantioselective catalysis.

Original language	English
Pages (from-to)	1963-1968
Number of pages	6
Journal	Chemistry - A European Journal
Volume	5
Issue number	7
DOIs	https://doi.org/10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4
State	Published - 1999
Externally published	Yes

Keywords

Asymmetric catalysis
C-C coupling
Cyclizations
Hydrovinylations
Ligand effects
Nickel
Palladium

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10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4

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title = "Hydrovinylation and related reactions: New protocols and control elements in search of greater synthetic efficiency and selectivity",

abstract = "New protocols for highly selective and nearly quantitative heterodimerization of ethylene or propylene with various functionalized vinylarenes are described. Under these conditions, which are compatible with a wide variety of functional groups, cylization of 1,6-dienes and hydrovinylation of norbornenes can also be accomplished. Also presented are possible strategies for stereo-chemical control, including a crucial role for hemilabile ligands in enantioselective catalysis.",

keywords = "Asymmetric catalysis, C-C coupling, Cyclizations, Hydrovinylations, Ligand effects, Nickel, Palladium",

author = "RajanBabu, \{T. V.\} and Nobuyoshi Nomura and Jian Jin and Branko Radetich and Haengsoon Park and Malay Nandi",

year = "1999",

doi = "10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4",

language = "English",

volume = "5",

pages = "1963--1968",

journal = "Chemistry - A European Journal",

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publisher = "John Wiley and Sons Inc.",

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}

TY - JOUR

T1 - Hydrovinylation and related reactions

T2 - New protocols and control elements in search of greater synthetic efficiency and selectivity

AU - RajanBabu, T. V.

AU - Nomura, Nobuyoshi

AU - Jin, Jian

AU - Radetich, Branko

AU - Park, Haengsoon

AU - Nandi, Malay

PY - 1999

Y1 - 1999

N2 - New protocols for highly selective and nearly quantitative heterodimerization of ethylene or propylene with various functionalized vinylarenes are described. Under these conditions, which are compatible with a wide variety of functional groups, cylization of 1,6-dienes and hydrovinylation of norbornenes can also be accomplished. Also presented are possible strategies for stereo-chemical control, including a crucial role for hemilabile ligands in enantioselective catalysis.

AB - New protocols for highly selective and nearly quantitative heterodimerization of ethylene or propylene with various functionalized vinylarenes are described. Under these conditions, which are compatible with a wide variety of functional groups, cylization of 1,6-dienes and hydrovinylation of norbornenes can also be accomplished. Also presented are possible strategies for stereo-chemical control, including a crucial role for hemilabile ligands in enantioselective catalysis.

KW - Asymmetric catalysis

KW - C-C coupling

KW - Cyclizations

KW - Hydrovinylations

KW - Ligand effects

KW - Nickel

KW - Palladium

UR - https://www.scopus.com/pages/publications/0033065027

U2 - 10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4

DO - 10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4

M3 - Article

AN - SCOPUS:0033065027

SN - 0947-6539

VL - 5

SP - 1963

EP - 1968

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 7

ER -

Hydrovinylation and related reactions: New protocols and control elements in search of greater synthetic efficiency and selectivity

Abstract

Keywords

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