Hydrovinylation and related reactions: New protocols and control elements in search of greater synthetic efficiency and selectivity

T. V. RajanBabu; Nobuyoshi Nomura; Jian Jin; Branko Radetich; Haengsoon Park; Malay Nandi

doi:10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4

Hydrovinylation and related reactions: New protocols and control elements in search of greater synthetic efficiency and selectivity

T. V. RajanBabu, Nobuyoshi Nomura, Jian Jin, Branko Radetich, Haengsoon Park, Malay Nandi

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75 Scopus citations

Abstract

New protocols for highly selective and nearly quantitative heterodimerization of ethylene or propylene with various functionalized vinylarenes are described. Under these conditions, which are compatible with a wide variety of functional groups, cylization of 1,6-dienes and hydrovinylation of norbornenes can also be accomplished. Also presented are possible strategies for stereo-chemical control, including a crucial role for hemilabile ligands in enantioselective catalysis.

Original language	English
Pages (from-to)	1963-1968
Number of pages	6
Journal	Chemistry - A European Journal
Volume	5
Issue number	7
DOIs	https://doi.org/10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4
State	Published - 1999
Externally published	Yes

Keywords

Asymmetric catalysis
C-C coupling
Cyclizations
Hydrovinylations
Ligand effects
Nickel
Palladium

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10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4

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title = "Hydrovinylation and related reactions: New protocols and control elements in search of greater synthetic efficiency and selectivity",

abstract = "New protocols for highly selective and nearly quantitative heterodimerization of ethylene or propylene with various functionalized vinylarenes are described. Under these conditions, which are compatible with a wide variety of functional groups, cylization of 1,6-dienes and hydrovinylation of norbornenes can also be accomplished. Also presented are possible strategies for stereo-chemical control, including a crucial role for hemilabile ligands in enantioselective catalysis.",

keywords = "Asymmetric catalysis, C-C coupling, Cyclizations, Hydrovinylations, Ligand effects, Nickel, Palladium",

author = "RajanBabu, \{T. V.\} and Nobuyoshi Nomura and Jian Jin and Branko Radetich and Haengsoon Park and Malay Nandi",

year = "1999",

doi = "10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4",

language = "English",

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journal = "Chemistry - A European Journal",

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TY - JOUR

T1 - Hydrovinylation and related reactions

T2 - New protocols and control elements in search of greater synthetic efficiency and selectivity

AU - RajanBabu, T. V.

AU - Nomura, Nobuyoshi

AU - Jin, Jian

AU - Radetich, Branko

AU - Park, Haengsoon

AU - Nandi, Malay

PY - 1999

Y1 - 1999

N2 - New protocols for highly selective and nearly quantitative heterodimerization of ethylene or propylene with various functionalized vinylarenes are described. Under these conditions, which are compatible with a wide variety of functional groups, cylization of 1,6-dienes and hydrovinylation of norbornenes can also be accomplished. Also presented are possible strategies for stereo-chemical control, including a crucial role for hemilabile ligands in enantioselective catalysis.

AB - New protocols for highly selective and nearly quantitative heterodimerization of ethylene or propylene with various functionalized vinylarenes are described. Under these conditions, which are compatible with a wide variety of functional groups, cylization of 1,6-dienes and hydrovinylation of norbornenes can also be accomplished. Also presented are possible strategies for stereo-chemical control, including a crucial role for hemilabile ligands in enantioselective catalysis.

KW - Asymmetric catalysis

KW - C-C coupling

KW - Cyclizations

KW - Hydrovinylations

KW - Ligand effects

KW - Nickel

KW - Palladium

UR - https://www.scopus.com/pages/publications/0033065027

U2 - 10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4

DO - 10.1002/(SICI)1521-3765(19990702)5:7<1963::AID-CHEM1963>3.0.CO;2-4

M3 - Article

AN - SCOPUS:0033065027

SN - 0947-6539

VL - 5

SP - 1963

EP - 1968

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 7

ER -

Hydrovinylation and related reactions: New protocols and control elements in search of greater synthetic efficiency and selectivity

Abstract

Keywords

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