TY - JOUR
T1 - Hydrothermal synthesis, structure and properties of a novel Zn(II) dicarboxylate containing nanometer channel by significant hydrogen bonds and π-π Interactions
AU - Zhu, Yong Min
AU - Wang, Peng
AU - Zhou, Hong Ping
AU - Yang, Jia Xiang
AU - Wu, Jie Ying
AU - Yang, Lin
AU - Tian, Yu Peng
AU - Jiang, Min Hua
AU - Tao, Xu Tang
N1 - Funding Information:
This work was supported by a grant for the National Natural Science Foundation of China (50532030, 50325311, 50335050), Doctoral Program Foundation of the Ministry of Education of China, Education Committee of Anhui Province (2006KJ032A, 2006KJ135B), Person with ability Foundation of An-hui Province (2002Z021), the Team for Scientific Innovation Foundation of Anhui Province (2006KJ 007TD), Key Laboratory of Opto-Electronic Information Acquisition and Manipulation, (Anhui University), Ministry of Education, Person with ability Foundation of Anhui Unversity.
PY - 2007/2
Y1 - 2007/2
N2 - A two-dimensional supramolecular complex, [Zn(HA)2(hmta)] • 2H2O (1) (H2A: 9-ethylcarbazole-3,6-dicarboxylic acid, hmta: 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane), has been prepared by hydrothermal synthesis and characterized by IR spectra, elemental analysis, TG analysis. The result of single crystal X-ray analysis revealed that the 2D supramolecular open framework contains 9.932 × 12.059 Å channels formed by significant hydrogen bonds and π-π interactions. Furthermore, the solid state fluorescent determinations show that the complex exhibits a strong emission band at 432 nm.
AB - A two-dimensional supramolecular complex, [Zn(HA)2(hmta)] • 2H2O (1) (H2A: 9-ethylcarbazole-3,6-dicarboxylic acid, hmta: 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane), has been prepared by hydrothermal synthesis and characterized by IR spectra, elemental analysis, TG analysis. The result of single crystal X-ray analysis revealed that the 2D supramolecular open framework contains 9.932 × 12.059 Å channels formed by significant hydrogen bonds and π-π interactions. Furthermore, the solid state fluorescent determinations show that the complex exhibits a strong emission band at 432 nm.
UR - https://www.scopus.com/pages/publications/33846553656
U2 - 10.1007/s11243-006-0140-z
DO - 10.1007/s11243-006-0140-z
M3 - Article
AN - SCOPUS:33846553656
SN - 0340-4285
VL - 32
SP - 136
EP - 139
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 1
ER -