FTIR structural investigation of gamma irradiated BaO-Na 2O-B 2O 3-SiO 2 glasses

Ravneet Kaur; Surinder Singh; Om Prakash Pandey

doi:10.1016/j.physb.2012.08.031

FTIR structural investigation of gamma irradiated BaO-Na ₂O-B ₂O ₃-SiO ₂ glasses

Ravneet Kaur, Surinder Singh, Om Prakash Pandey

Research output: Contribution to journal › Article › peer-review

80 Scopus citations

Abstract

Fourier transform infrared (FT-IR) spectra of xBaO-15Na ₂O-(70-x) B ₂O ₃-15SiO ₂ glass system with x=0, 5, 10, 15 and 20 (mol) has been measured in the spectral range 400-4000 cm ^-1 at room temperature in order to understand the characteristic frequencies of the chemical bonds and bonding mechanisms, which are susceptible to the structural and spectral changes. The effect of gamma irradiation in the dose range 0.1 kGy-60 kGy on the infrared absorption spectra of these glasses is also reported. The change in the glass structure due to the effect of composition is also discussed. It has been observed that irradiation of the glasses with the gamma rays increases the BO ₃ groups and the non bridging oxygens which make the network loose.

Original language	English
Pages (from-to)	4765-4769
Number of pages	5
Journal	Physica B: Condensed Matter
Volume	407
Issue number	24
DOIs	https://doi.org/10.1016/j.physb.2012.08.031
State	Published - 15 Dec 2012
Externally published	Yes

Keywords

Barium
Borosilicate glasses
FT-IR Spectroscopy
Gamma irradiation
NBOs
Radiation damage

Access to Document

10.1016/j.physb.2012.08.031

Cite this

@article{e492c6e167544a01b80855136faf4a02,

title = "FTIR structural investigation of gamma irradiated BaO-Na 2O-B 2O 3-SiO 2 glasses",

abstract = "Fourier transform infrared (FT-IR) spectra of xBaO-15Na 2O-(70-x) B 2O 3-15SiO 2 glass system with x=0, 5, 10, 15 and 20 (mol) has been measured in the spectral range 400-4000 cm -1 at room temperature in order to understand the characteristic frequencies of the chemical bonds and bonding mechanisms, which are susceptible to the structural and spectral changes. The effect of gamma irradiation in the dose range 0.1 kGy-60 kGy on the infrared absorption spectra of these glasses is also reported. The change in the glass structure due to the effect of composition is also discussed. It has been observed that irradiation of the glasses with the gamma rays increases the BO 3 groups and the non bridging oxygens which make the network loose.",

keywords = "Barium, Borosilicate glasses, FT-IR Spectroscopy, Gamma irradiation, NBOs, Radiation damage",

author = "Ravneet Kaur and Surinder Singh and Pandey, {Om Prakash}",

note = "Funding Information: The authors are thankful to the IUAC, New Delhi for providing the financial assistance and necessary experimental facilities for the completion of this work.",

year = "2012",

month = dec,

day = "15",

doi = "10.1016/j.physb.2012.08.031",

language = "English",

volume = "407",

pages = "4765--4769",

journal = "Physica B: Condensed Matter",

issn = "0921-4526",

publisher = "Elsevier B.V.",

number = "24",

}

TY - JOUR

T1 - FTIR structural investigation of gamma irradiated BaO-Na 2O-B 2O 3-SiO 2 glasses

AU - Kaur, Ravneet

AU - Singh, Surinder

AU - Pandey, Om Prakash

N1 - Funding Information: The authors are thankful to the IUAC, New Delhi for providing the financial assistance and necessary experimental facilities for the completion of this work.

PY - 2012/12/15

Y1 - 2012/12/15

N2 - Fourier transform infrared (FT-IR) spectra of xBaO-15Na 2O-(70-x) B 2O 3-15SiO 2 glass system with x=0, 5, 10, 15 and 20 (mol) has been measured in the spectral range 400-4000 cm -1 at room temperature in order to understand the characteristic frequencies of the chemical bonds and bonding mechanisms, which are susceptible to the structural and spectral changes. The effect of gamma irradiation in the dose range 0.1 kGy-60 kGy on the infrared absorption spectra of these glasses is also reported. The change in the glass structure due to the effect of composition is also discussed. It has been observed that irradiation of the glasses with the gamma rays increases the BO 3 groups and the non bridging oxygens which make the network loose.

AB - Fourier transform infrared (FT-IR) spectra of xBaO-15Na 2O-(70-x) B 2O 3-15SiO 2 glass system with x=0, 5, 10, 15 and 20 (mol) has been measured in the spectral range 400-4000 cm -1 at room temperature in order to understand the characteristic frequencies of the chemical bonds and bonding mechanisms, which are susceptible to the structural and spectral changes. The effect of gamma irradiation in the dose range 0.1 kGy-60 kGy on the infrared absorption spectra of these glasses is also reported. The change in the glass structure due to the effect of composition is also discussed. It has been observed that irradiation of the glasses with the gamma rays increases the BO 3 groups and the non bridging oxygens which make the network loose.

KW - Barium

KW - Borosilicate glasses

KW - FT-IR Spectroscopy

KW - Gamma irradiation

KW - NBOs

KW - Radiation damage

UR - http://www.scopus.com/inward/record.url?scp=84868355646&partnerID=8YFLogxK

U2 - 10.1016/j.physb.2012.08.031

DO - 10.1016/j.physb.2012.08.031

M3 - Article

AN - SCOPUS:84868355646

SN - 0921-4526

VL - 407

SP - 4765

EP - 4769

JO - Physica B: Condensed Matter

JF - Physica B: Condensed Matter

IS - 24