Enantioselective first total syntheses of 2-(formylamino)trachyopsane and ent-2-(isocyano)trachyopsane via a biomimetic approach

A. Srikrishna; G. Ravi; D. R.C. Venkata Subbaiah

doi:10.1055/s-0028-1087382

Enantioselective first total syntheses of 2-(formylamino)trachyopsane and ent-2-(isocyano)trachyopsane via a biomimetic approach

A. Srikrishna
, G. Ravi
, D. R.C. Venkata Subbaiah

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A biomimetic rearrangement of an isotwistane to a tricyclo[4.3.1.0 ^3,8]decane has been employed as the key step for the enantioselective first total syntheses of the marine sesquiterpenes 2-(formylamino)trachyopsane and ent-2-(isocyano)trachyopsanes ascertaining the biogenetic relationship between the marine sesquiterpenes neopupukeananes and trachyopsanes.

Original language	English
Pages (from-to)	32-34
Number of pages	3
Journal	Synlett
Issue number	1
DOIs	https://doi.org/10.1055/s-0028-1087382
State	Published - Jan 2009
Externally published	Yes

Keywords

Acid-catalysed rearrangement
Biomimetic synthesis
Enantioselective synthesis
Marine sesquiterpenes
Natural products

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10.1055/s-0028-1087382

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title = "Enantioselective first total syntheses of 2-(formylamino)trachyopsane and ent-2-(isocyano)trachyopsane via a biomimetic approach",

abstract = "A biomimetic rearrangement of an isotwistane to a tricyclo[4.3.1.0 3,8]decane has been employed as the key step for the enantioselective first total syntheses of the marine sesquiterpenes 2-(formylamino)trachyopsane and ent-2-(isocyano)trachyopsanes ascertaining the biogenetic relationship between the marine sesquiterpenes neopupukeananes and trachyopsanes.",

keywords = "Acid-catalysed rearrangement, Biomimetic synthesis, Enantioselective synthesis, Marine sesquiterpenes, Natural products",

author = "A. Srikrishna and G. Ravi and \{Venkata Subbaiah\}, \{D. R.C.\}",

year = "2009",

month = jan,

doi = "10.1055/s-0028-1087382",

language = "English",

pages = "32--34",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

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T1 - Enantioselective first total syntheses of 2-(formylamino)trachyopsane and ent-2-(isocyano)trachyopsane via a biomimetic approach

AU - Srikrishna, A.

AU - Ravi, G.

AU - Venkata Subbaiah, D. R.C.

PY - 2009/1

Y1 - 2009/1

N2 - A biomimetic rearrangement of an isotwistane to a tricyclo[4.3.1.0 3,8]decane has been employed as the key step for the enantioselective first total syntheses of the marine sesquiterpenes 2-(formylamino)trachyopsane and ent-2-(isocyano)trachyopsanes ascertaining the biogenetic relationship between the marine sesquiterpenes neopupukeananes and trachyopsanes.

AB - A biomimetic rearrangement of an isotwistane to a tricyclo[4.3.1.0 3,8]decane has been employed as the key step for the enantioselective first total syntheses of the marine sesquiterpenes 2-(formylamino)trachyopsane and ent-2-(isocyano)trachyopsanes ascertaining the biogenetic relationship between the marine sesquiterpenes neopupukeananes and trachyopsanes.

KW - Acid-catalysed rearrangement

KW - Biomimetic synthesis

KW - Enantioselective synthesis

KW - Marine sesquiterpenes

KW - Natural products

UR - https://www.scopus.com/pages/publications/62349124195

U2 - 10.1055/s-0028-1087382

DO - 10.1055/s-0028-1087382

M3 - Article

AN - SCOPUS:62349124195

SN - 0936-5214

SP - 32

EP - 34

JO - Synlett

JF - Synlett

IS - 1

ER -

Enantioselective first total syntheses of 2-(formylamino)trachyopsane and ent-2-(isocyano)trachyopsane via a biomimetic approach

Abstract

Keywords

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