Electrochemical and electrocatalytic properties of polypyrrole film doped with heteropolyanions

Peng Wang; Yongfang Li

doi:10.1016/0022-0728(95)04445-0

Electrochemical and electrocatalytic properties of polypyrrole film doped with heteropolyanions

Peng Wang, Yongfang Li

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

Electrically conducting polypyrrole (PPy) doped with heteropolyanions (HPA) [PMo₁₂O₄₀]^3-was synthesized by electrochemical polymerization. The electrical conductivity could be as high as 10⁰ S cm^-1. Cyclic voltammograms showed reversible redox peaks from the polymer itself and from the immobilized HPA. Electrochemical quartz crystal microbalance measurement indicated that the anions were retained in the polymer matrix without being replaced after repeated potential cycles in electrolyte solutions containing no HPA. We also examined the electrocatalytic effects of the electrodes modified by this PPy + HPA film on the reduction of oxygen and chlorate.

Original language	English
Pages (from-to)	77-81
Number of pages	5
Journal	Journal of Electroanalytical Chemistry
Volume	408
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-0728(95)04445-0
State	Published - 30 May 1996
Externally published	Yes

Keywords

Electrocatalysis
Electropolymerization
Heteropolyanion
Polypyrrole

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10.1016/0022-0728(95)04445-0

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title = "Electrochemical and electrocatalytic properties of polypyrrole film doped with heteropolyanions",

abstract = "Electrically conducting polypyrrole (PPy) doped with heteropolyanions (HPA) [PMo12O40]3-was synthesized by electrochemical polymerization. The electrical conductivity could be as high as 100 S cm-1. Cyclic voltammograms showed reversible redox peaks from the polymer itself and from the immobilized HPA. Electrochemical quartz crystal microbalance measurement indicated that the anions were retained in the polymer matrix without being replaced after repeated potential cycles in electrolyte solutions containing no HPA. We also examined the electrocatalytic effects of the electrodes modified by this PPy + HPA film on the reduction of oxygen and chlorate.",

keywords = "Electrocatalysis, Electropolymerization, Heteropolyanion, Polypyrrole",

author = "Peng Wang and Yongfang Li",

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doi = "10.1016/0022-0728(95)04445-0",

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T1 - Electrochemical and electrocatalytic properties of polypyrrole film doped with heteropolyanions

AU - Wang, Peng

AU - Li, Yongfang

PY - 1996/5/30

Y1 - 1996/5/30

N2 - Electrically conducting polypyrrole (PPy) doped with heteropolyanions (HPA) [PMo12O40]3-was synthesized by electrochemical polymerization. The electrical conductivity could be as high as 100 S cm-1. Cyclic voltammograms showed reversible redox peaks from the polymer itself and from the immobilized HPA. Electrochemical quartz crystal microbalance measurement indicated that the anions were retained in the polymer matrix without being replaced after repeated potential cycles in electrolyte solutions containing no HPA. We also examined the electrocatalytic effects of the electrodes modified by this PPy + HPA film on the reduction of oxygen and chlorate.

AB - Electrically conducting polypyrrole (PPy) doped with heteropolyanions (HPA) [PMo12O40]3-was synthesized by electrochemical polymerization. The electrical conductivity could be as high as 100 S cm-1. Cyclic voltammograms showed reversible redox peaks from the polymer itself and from the immobilized HPA. Electrochemical quartz crystal microbalance measurement indicated that the anions were retained in the polymer matrix without being replaced after repeated potential cycles in electrolyte solutions containing no HPA. We also examined the electrocatalytic effects of the electrodes modified by this PPy + HPA film on the reduction of oxygen and chlorate.

KW - Electrocatalysis

KW - Electropolymerization

KW - Heteropolyanion

KW - Polypyrrole

UR - http://www.scopus.com/inward/record.url?scp=0030148668&partnerID=8YFLogxK

U2 - 10.1016/0022-0728(95)04445-0

DO - 10.1016/0022-0728(95)04445-0

M3 - Article

AN - SCOPUS:0030148668

SN - 1572-6657

VL - 408

SP - 77

EP - 81

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 1-2

ER -

Electrochemical and electrocatalytic properties of polypyrrole film doped with heteropolyanions

Abstract

Keywords

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