Direct observation of molecular orbital mixing in a solvated organometallic complex

Edlira Suljoti; Raul Garcia-Diez; Sergey I. Bokarev; Kathrin M. Lange; Roland Schoch; Brian Dierker; Marcus Dantz; Kenji Yamamoto; Nicholas Engel; Kaan Atak; Oliver Kühn; Matthias Bauer; Jan Erik Rubensson; Emad F. Aziz

doi:10.1002/anie.201303310

Direct observation of molecular orbital mixing in a solvated organometallic complex

Edlira Suljoti
, Raul Garcia-Diez
, Sergey I. Bokarev
, Kathrin M. Lange
, Roland Schoch
, Brian Dierker
, Marcus Dantz
, Kenji Yamamoto
, Nicholas Engel
, Kaan Atak
, Oliver Kühn
, Matthias Bauer
, Jan Erik Rubensson
, Emad F. Aziz

Research output: Contribution to journal › Article › peer-review

63 Scopus citations

Abstract

Fundamental processes: Charge donation/backdonation in the [Fe(CO) ₅] molecule in solution was measured by resonant inelastic X-ray scattering. This method can be used to selectively probe the electronic structure at each atom in the iron-carbonyl bond.

Original language	English
Pages (from-to)	9841-9844
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	37
DOIs	https://doi.org/10.1002/anie.201303310
State	Published - 9 Sep 2013
Externally published	Yes

Keywords

X-ray spectroscopy
backdonation
organometallic complexes
resonant inelastic X-ray scattering

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10.1002/anie.201303310

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Suljoti, E., Garcia-Diez, R., Bokarev, S. I., Lange, K. M., Schoch, R., Dierker, B., Dantz, M., Yamamoto, K., Engel, N., Atak, K., Kühn, O., Bauer, M., Rubensson, J. E., & Aziz, E. F. (2013). Direct observation of molecular orbital mixing in a solvated organometallic complex. Angewandte Chemie - International Edition, 52(37), 9841-9844. https://doi.org/10.1002/anie.201303310

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abstract = "Fundamental processes: Charge donation/backdonation in the [Fe(CO) 5] molecule in solution was measured by resonant inelastic X-ray scattering. This method can be used to selectively probe the electronic structure at each atom in the iron-carbonyl bond.",

keywords = "X-ray spectroscopy, backdonation, organometallic complexes, resonant inelastic X-ray scattering",

author = "Edlira Suljoti and Raul Garcia-Diez and Bokarev, \{Sergey I.\} and Lange, \{Kathrin M.\} and Roland Schoch and Brian Dierker and Marcus Dantz and Kenji Yamamoto and Nicholas Engel and Kaan Atak and Oliver K{\"u}hn and Matthias Bauer and Rubensson, \{Jan Erik\} and Aziz, \{Emad F.\}",

year = "2013",

month = sep,

day = "9",

doi = "10.1002/anie.201303310",

language = "English",

volume = "52",

pages = "9841--9844",

journal = "Angewandte Chemie - International Edition",

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T1 - Direct observation of molecular orbital mixing in a solvated organometallic complex

AU - Suljoti, Edlira

AU - Garcia-Diez, Raul

AU - Bokarev, Sergey I.

AU - Lange, Kathrin M.

AU - Schoch, Roland

AU - Dierker, Brian

AU - Dantz, Marcus

AU - Yamamoto, Kenji

AU - Engel, Nicholas

AU - Atak, Kaan

AU - Kühn, Oliver

AU - Bauer, Matthias

AU - Rubensson, Jan Erik

AU - Aziz, Emad F.

PY - 2013/9/9

Y1 - 2013/9/9

N2 - Fundamental processes: Charge donation/backdonation in the [Fe(CO) 5] molecule in solution was measured by resonant inelastic X-ray scattering. This method can be used to selectively probe the electronic structure at each atom in the iron-carbonyl bond.

AB - Fundamental processes: Charge donation/backdonation in the [Fe(CO) 5] molecule in solution was measured by resonant inelastic X-ray scattering. This method can be used to selectively probe the electronic structure at each atom in the iron-carbonyl bond.

KW - X-ray spectroscopy

KW - backdonation

KW - organometallic complexes

KW - resonant inelastic X-ray scattering

UR - https://www.scopus.com/pages/publications/84883494365

U2 - 10.1002/anie.201303310

DO - 10.1002/anie.201303310

M3 - Article

AN - SCOPUS:84883494365

SN - 1433-7851

VL - 52

SP - 9841

EP - 9844

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 37

ER -

Direct observation of molecular orbital mixing in a solvated organometallic complex

Abstract

Keywords

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