Biocatalytic polytransesterification of inulin with divinyladipate

Lino Ferreira; Maria H. Gil; Rui Carvalho; Carlos F.G.C. Geraldes; Dae Yun Kim; Jonathan S. Dordick

doi:10.1021/cm020393w

Biocatalytic polytransesterification of inulin with divinyladipate

Lino Ferreira
, Maria H. Gil
, Rui Carvalho
, Carlos F.G.C. Geraldes
, Dae Yun Kim
, Jonathan S. Dordick

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

This work was directed at extending the use of enzyme-catalyzed polytransesterification reactions to a polysaccharide. Inulin polyesters with M_n greater than 20 000 Da (corresponding to the polymerization of five units of inulin) were obtained with DVA molecules attached to the inulin backbone at the 6-position on the fructofuranoside residue, mainly by both ester termini (R₂) and by a small extent through single ester termini (R₁).

Original language	English
Pages (from-to)	4009-4011
Number of pages	3
Journal	Chemistry of Materials
Volume	14
Issue number	10
DOIs	https://doi.org/10.1021/cm020393w
State	Published - 1 Oct 2002
Externally published	Yes

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title = "Biocatalytic polytransesterification of inulin with divinyladipate",

abstract = "This work was directed at extending the use of enzyme-catalyzed polytransesterification reactions to a polysaccharide. Inulin polyesters with Mn greater than 20 000 Da (corresponding to the polymerization of five units of inulin) were obtained with DVA molecules attached to the inulin backbone at the 6-position on the fructofuranoside residue, mainly by both ester termini (R2) and by a small extent through single ester termini (R1).",

author = "Lino Ferreira and Gil, \{Maria H.\} and Rui Carvalho and Geraldes, \{Carlos F.G.C.\} and Kim, \{Dae Yun\} and Dordick, \{Jonathan S.\}",

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doi = "10.1021/cm020393w",

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T1 - Biocatalytic polytransesterification of inulin with divinyladipate

AU - Ferreira, Lino

AU - Gil, Maria H.

AU - Carvalho, Rui

AU - Geraldes, Carlos F.G.C.

AU - Kim, Dae Yun

AU - Dordick, Jonathan S.

PY - 2002/10/1

Y1 - 2002/10/1

N2 - This work was directed at extending the use of enzyme-catalyzed polytransesterification reactions to a polysaccharide. Inulin polyesters with Mn greater than 20 000 Da (corresponding to the polymerization of five units of inulin) were obtained with DVA molecules attached to the inulin backbone at the 6-position on the fructofuranoside residue, mainly by both ester termini (R2) and by a small extent through single ester termini (R1).

AB - This work was directed at extending the use of enzyme-catalyzed polytransesterification reactions to a polysaccharide. Inulin polyesters with Mn greater than 20 000 Da (corresponding to the polymerization of five units of inulin) were obtained with DVA molecules attached to the inulin backbone at the 6-position on the fructofuranoside residue, mainly by both ester termini (R2) and by a small extent through single ester termini (R1).

UR - https://www.scopus.com/pages/publications/0036799646

U2 - 10.1021/cm020393w

DO - 10.1021/cm020393w

M3 - Article

AN - SCOPUS:0036799646

SN - 0897-4756

VL - 14

SP - 4009

EP - 4011

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 10

ER -

Biocatalytic polytransesterification of inulin with divinyladipate

Abstract

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