TY - JOUR
T1 - A novel 2D Mn(II) dicarboxylate with nanometer channels
T2 - Hydrothermal synthesis, crystal structures and luminescence properties
AU - Zhu, Yong Min
AU - Li, Wei Jie
AU - Lv, Liang Fei
AU - Wang, Peng
AU - Wu, Jie Ying
AU - Yang, Jia Xiang
AU - Zhou, Hong Ping
AU - Tian, Yu Peng
AU - Jiang, Min Hua
AU - Tao, Xu Tang
N1 - Funding Information:
This work was supported by a grant for the National Natural Science Foundation of China (50532030, 50325311, 50335050), Doctoral Program Foundation of the Ministry of Education of China, Education Committee of Anhui Province (2006KJ032A, 2006KJ135B), Person with ability Foundation of Anhui Province (2002Z021), the Team for Scientific Innovation Foundation of Anhui Province (2006KJ007TD), Key Laboratory of Opto-Electronic Information Acquisition and Manipulation, (Anhui University), Ministry of Education, Person with Ability Foundation of Anhui University.
PY - 2007/10
Y1 - 2007/10
N2 - A novel two-dimensional supramolecular complex, Mn(HA)2(H 2O)2 (1) (H2A: 9-ethylcarbazole-3,6- dicarboxylic acid) has been prepared by hydrothermal synthetic method and characterized by X-ray single crystal diffraction, IR spectra, elemental analysis and TG analysis. The result confirms that complex (1) crystallizes in the space group C2/c with a = 31.30(2) Å, b = 5.088(4) Å, c = 20.517(14) Å, β = 119.863(9)°, Z = 4, V = 2834(3) Å3. The 2D supramolecular open framework (1), which contains 9.773 × 7.447 Å nanometer channels, is constructed through hydrogen bonds and aromatic π - π interactions. Furthermore, the solid-state fluorescent analyses show that complex 1 exhibits a broad emission with the maximal emission at 416 nm.
AB - A novel two-dimensional supramolecular complex, Mn(HA)2(H 2O)2 (1) (H2A: 9-ethylcarbazole-3,6- dicarboxylic acid) has been prepared by hydrothermal synthetic method and characterized by X-ray single crystal diffraction, IR spectra, elemental analysis and TG analysis. The result confirms that complex (1) crystallizes in the space group C2/c with a = 31.30(2) Å, b = 5.088(4) Å, c = 20.517(14) Å, β = 119.863(9)°, Z = 4, V = 2834(3) Å3. The 2D supramolecular open framework (1), which contains 9.773 × 7.447 Å nanometer channels, is constructed through hydrogen bonds and aromatic π - π interactions. Furthermore, the solid-state fluorescent analyses show that complex 1 exhibits a broad emission with the maximal emission at 416 nm.
UR - https://www.scopus.com/pages/publications/34547910707
U2 - 10.1007/s11243-007-0267-6
DO - 10.1007/s11243-007-0267-6
M3 - Article
AN - SCOPUS:34547910707
SN - 0340-4285
VL - 32
SP - 967
EP - 970
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 7
ER -