A new series of Ru(II) polypyridine surfactants: Synthesis, 2D NMR, fluorescence, electrochemistry and electrochemiluminescence

Peng Wang, Guoyi Zhu

Research output: Contribution to journalArticlepeer-review

Abstract

A new series of Ru(II) polypyridine surfactants, Ru(bpy)2[phenNH CO(CH2)nCH3](PF6)2, where n is 10, 12, 14 or 16, has been prepared and characterized. The 1H-NMR spectra of these new Ru(II) complexes were attributed and discussed by the 1H-1H COSY method. The comparative analysis of IR spectra of these complexes and their responding free ligands has shown that there are intensive d → π* feédback interactions between central Ru(II) and their ligands. Their fluorescent, electrochemical and electrochemiluminescent behaviours are also reported.

Original languageEnglish
Pages (from-to)1307-1312
Number of pages6
JournalAsian Journal of Chemistry
Volume11
Issue number4
StatePublished - 1999
Externally publishedYes

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