A new ligand for the formation of a 3D structure by C-H···O, O-H···O hydrogen-bonds and π-π interactions

Hong Ping Zhou; Peng Wang; Fu Ying Hao; Hai Peng Ye; Qiong Zhao; Rui Long Zhang; Yu Peng Tian; Jie Ying Wu; Xu Tang Tao; Min Hua Jiang

doi:10.1016/j.molstruc.2008.05.042

A new ligand for the formation of a 3D structure by C-H···O, O-H···O hydrogen-bonds and π-π interactions

Hong Ping Zhou
, Peng Wang
, Fu Ying Hao
, Hai Peng Ye
, Qiong Zhao
, Rui Long Zhang
, Yu Peng Tian
, Jie Ying Wu
, Xu Tang Tao
, Min Hua Jiang

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A new functional flexible ligand: 3,6-di-(1,2,4-triazole-1-yl)-N-ethyl carbazole (L) and Co (II) coordination polymer (1) have been synthesized and investigated. Single crystal X-ray analysis has revealed that the 3D coordination polymer is formed by interchains OH···O and CH···O hydrogen-bonds, interlayers CH···O hydrogen-bonds and π-π interactions. NO₃^- and H₂O play an important role in constructing 3D supramolecular architectures. The blue emissions from solid fluorescence indicate that the coordination complex 1 is a promising candidate for application in optoelectronic devices.

Original language	English
Pages (from-to)	316-319
Number of pages	4
Journal	Journal of Molecular Structure
Volume	892
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2008.05.042
State	Published - 15 Dec 2008
Externally published	Yes

Keywords

Coordination polymer
Fluorescence
Hydrogen-bonds
X-ray diffraction

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10.1016/j.molstruc.2008.05.042

Cite this

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title = "A new ligand for the formation of a 3D structure by C-H···O, O-H···O hydrogen-bonds and π-π interactions",

abstract = "A new functional flexible ligand: 3,6-di-(1,2,4-triazole-1-yl)-N-ethyl carbazole (L) and Co (II) coordination polymer (1) have been synthesized and investigated. Single crystal X-ray analysis has revealed that the 3D coordination polymer is formed by interchains OH···O and CH···O hydrogen-bonds, interlayers CH···O hydrogen-bonds and π-π interactions. NO3- and H2O play an important role in constructing 3D supramolecular architectures. The blue emissions from solid fluorescence indicate that the coordination complex 1 is a promising candidate for application in optoelectronic devices.",

keywords = "Coordination polymer, Fluorescence, Hydrogen-bonds, X-ray diffraction",

author = "Zhou, \{Hong Ping\} and Peng Wang and Hao, \{Fu Ying\} and Ye, \{Hai Peng\} and Qiong Zhao and Zhang, \{Rui Long\} and Tian, \{Yu Peng\} and Wu, \{Jie Ying\} and Tao, \{Xu Tang\} and Jiang, \{Min Hua\}",

year = "2008",

month = dec,

day = "15",

doi = "10.1016/j.molstruc.2008.05.042",

language = "English",

volume = "892",

pages = "316--319",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - A new ligand for the formation of a 3D structure by C-H···O, O-H···O hydrogen-bonds and π-π interactions

AU - Zhou, Hong Ping

AU - Wang, Peng

AU - Hao, Fu Ying

AU - Ye, Hai Peng

AU - Zhao, Qiong

AU - Zhang, Rui Long

AU - Tian, Yu Peng

AU - Wu, Jie Ying

AU - Tao, Xu Tang

AU - Jiang, Min Hua

PY - 2008/12/15

Y1 - 2008/12/15

N2 - A new functional flexible ligand: 3,6-di-(1,2,4-triazole-1-yl)-N-ethyl carbazole (L) and Co (II) coordination polymer (1) have been synthesized and investigated. Single crystal X-ray analysis has revealed that the 3D coordination polymer is formed by interchains OH···O and CH···O hydrogen-bonds, interlayers CH···O hydrogen-bonds and π-π interactions. NO3- and H2O play an important role in constructing 3D supramolecular architectures. The blue emissions from solid fluorescence indicate that the coordination complex 1 is a promising candidate for application in optoelectronic devices.

AB - A new functional flexible ligand: 3,6-di-(1,2,4-triazole-1-yl)-N-ethyl carbazole (L) and Co (II) coordination polymer (1) have been synthesized and investigated. Single crystal X-ray analysis has revealed that the 3D coordination polymer is formed by interchains OH···O and CH···O hydrogen-bonds, interlayers CH···O hydrogen-bonds and π-π interactions. NO3- and H2O play an important role in constructing 3D supramolecular architectures. The blue emissions from solid fluorescence indicate that the coordination complex 1 is a promising candidate for application in optoelectronic devices.

KW - Coordination polymer

KW - Fluorescence

KW - Hydrogen-bonds

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/55749106934

U2 - 10.1016/j.molstruc.2008.05.042

DO - 10.1016/j.molstruc.2008.05.042

M3 - Article

AN - SCOPUS:55749106934

SN - 0022-2860

VL - 892

SP - 316

EP - 319

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

A new ligand for the formation of a 3D structure by C-H···O, O-H···O hydrogen-bonds and π-π interactions

Abstract

Keywords

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