A general method for the stereospecific synthesis of C-glycosides of ulosonic acids by samarium-mediated reductive dechlorination

Tülay Polat; Yuguo Du; Robert J. Linhardt

doi:10.1055/s-1998-1923

A general method for the stereospecific synthesis of C-glycosides of ulosonic acids by samarium-mediated reductive dechlorination

Tülay Polat, Yuguo Du, Robert J. Linhardt

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28 Scopus citations

Abstract

C-glycosylation reactions were performed with the 2-chloro derivatives of NANA, KDN and KDO. C-glycosides were obtained when carbonyl compounds (ketone or sugar aldehyde) were coupled to the 2-chloro-derivatives of these ulosonic acids under Barbier conditions.

Original language	English
Pages (from-to)	1195-1196
Number of pages	2
Journal	Synlett
Issue number	11
DOIs	https://doi.org/10.1055/s-1998-1923
State	Published - Nov 1998
Externally published	Yes

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title = "A general method for the stereospecific synthesis of C-glycosides of ulosonic acids by samarium-mediated reductive dechlorination",

abstract = "C-glycosylation reactions were performed with the 2-chloro derivatives of NANA, KDN and KDO. C-glycosides were obtained when carbonyl compounds (ketone or sugar aldehyde) were coupled to the 2-chloro-derivatives of these ulosonic acids under Barbier conditions.",

author = "T{\"u}lay Polat and Yuguo Du and Linhardt, {Robert J.}",

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AU - Du, Yuguo

AU - Linhardt, Robert J.

PY - 1998/11

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N2 - C-glycosylation reactions were performed with the 2-chloro derivatives of NANA, KDN and KDO. C-glycosides were obtained when carbonyl compounds (ketone or sugar aldehyde) were coupled to the 2-chloro-derivatives of these ulosonic acids under Barbier conditions.

AB - C-glycosylation reactions were performed with the 2-chloro derivatives of NANA, KDN and KDO. C-glycosides were obtained when carbonyl compounds (ketone or sugar aldehyde) were coupled to the 2-chloro-derivatives of these ulosonic acids under Barbier conditions.

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U2 - 10.1055/s-1998-1923

DO - 10.1055/s-1998-1923

M3 - Article

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SN - 0936-5214

SP - 1195

EP - 1196

JO - Synlett

JF - Synlett

IS - 11

ER -

A general method for the stereospecific synthesis of C-glycosides of ulosonic acids by samarium-mediated reductive dechlorination

Abstract

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