TY - JOUR
T1 - 5-(2-Methyl-phen-yl)-1,3,4-thia-diazol-2-amine
AU - Wang, Yao
AU - Kong, Xiang Jun
AU - Wan, Rong
AU - Han, Feng
AU - Wang, Peng
PY - 2009
Y1 - 2009
N2 - The asymmetric unit of the title compound, C9H9N 3S, contains two crystallographically independent mol-ecules, in which the thia-diazole and tolyl rings are oriented at dihedral angles of 32.25 (3) and 74.50 (3)°. An intra-molecular C - H⋯S inter-action results in the formation of a five-membered ring. In the crystal structure, inter-molecular N - H⋯N hydrogen bonds link the mol-ecules into chains along the a axis. A π-π contact between the thia-diazole rings [centroid-centroid distance = 3.910 (3) Å] may further stabilize the structure. There is also a weak C - H⋯π inter-action.
AB - The asymmetric unit of the title compound, C9H9N 3S, contains two crystallographically independent mol-ecules, in which the thia-diazole and tolyl rings are oriented at dihedral angles of 32.25 (3) and 74.50 (3)°. An intra-molecular C - H⋯S inter-action results in the formation of a five-membered ring. In the crystal structure, inter-molecular N - H⋯N hydrogen bonds link the mol-ecules into chains along the a axis. A π-π contact between the thia-diazole rings [centroid-centroid distance = 3.910 (3) Å] may further stabilize the structure. There is also a weak C - H⋯π inter-action.
UR - https://www.scopus.com/pages/publications/66749103326
U2 - 10.1107/S1600536809011234
DO - 10.1107/S1600536809011234
M3 - Article
AN - SCOPUS:66749103326
SN - 1600-5368
VL - 65
SP - o961
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 5
ER -